Sparkes, Emily I.; Egedeuzu, Chisom S.; Lias, Billie; Sung, Rehana; Caslin, Stephanie A.; Tabatabaei Dakhili, S. Yasin; Taylor, Peter G.; Quayle, Peter; Wong, Lu Shin published an article in 2021. The article was titled 《Biocatalytic Silylation: The Condensation of Phenols and Alcohols with Triethylsilanol》, and you may find the article in Catalysts.Recommanded Product: m-Methoxyphenol The information in the text is summarized as follows:
Silicatein-α (Silα), a hydrolytic enzyme derived from siliceous marine sponges, is one of the few enzymes in nature capable of catalyzing the metathesis of silicon-oxygen bonds. It is therefore of interest as a possible biocatalyst for the synthesis of organosiloxanes. To further investigate the substrate scope of this enzyme, a series of condensation reactions with a variety of phenols and aliphatic alcs. were carried out. In general, it was observed that Silα demonstrated a preference for phenols, though the conversions were relatively modest in most cases. In the two pairs of chiral alcs. that were investigated, it was found that the enzyme displayed a preference for the silylation of the S-enantiomers. Addnl., the enzyme′s tolerance to a range of solvents was tested. Silα had the highest level of substrate conversion in the nonpolar solvents n-octane and toluene, although the inclusion of up to 20% of 1,4-dioxane was tolerated. These results suggest that Silα is a potential candidate for directed evolution toward future application as a robust and selective biocatalyst for organosiloxane chem. The experimental process involved the reaction of m-Methoxyphenol(cas: 150-19-6Recommanded Product: m-Methoxyphenol)
m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Recommanded Product: m-Methoxyphenol
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem