Synthetic Route of C12H10S2In 2019 ,《Fe(III)-Catalyzed direct C3 chalcogenylation of indole: the effect of iodide ions》 was published in Tetrahedron. The article was written by Luz, Eduardo Q.; Seckler, Diego; Araujo, Janylson Souza; Angst, Leonardo; Lima, David B.; Maluf Rios, Elise Ane; Ribeiro, Ronny R.; Rampon, Daniel S.. The article contains the following contents:
A mild and efficient protocol for the synthesis of selenyl/sulfenyl-indoles I [R = H, Me, SPh, SePh; R1 = H, Me, Bn; R2 = Me, SPh, SePh, etc.] was developed via iron (III)-catalyzed C3 chalcogenylation of indoles with (diaryl)disulfides/diselenides and the role of the iodide ions in this transformation was investigated. EPR experiments revealed the reduction of Fe(III) to Fe(II) under the reaction conditions, supported the formation of mol. iodine in the system, which in effect catalyze the reaction. The scope of the chalcogenylation was broad. In the experiment, the researchers used many compounds, for example, 1,2-Diphenyldisulfane(cas: 882-33-7Synthetic Route of C12H10S2)
1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.Synthetic Route of C12H10S2Although ethers resist hydrolysis, they are cleaved by hydrobromic acid and hydroiodic acid. Hydrogen chloride cleaves ethers only slowly.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem