Recommanded Product: 1,2-DiphenyldisulfaneIn 2019 ,《Catalyst-Free gem-Difunctionalization of Fluoroalkyl-Substituted Diazo Compound with Diselenide or Disulfide and NFSI》 was published in Organic Letters. The article was written by Li, Jiuling; Ma, Chaoqun; Xing, Dong; Hu, Wenhao. The article contains the following contents:
Diazo compounds such as F3CCH:N2 underwent difunctionalization reactions with diselenides, disulfides, or di-Ph ditelluride and N-fluorobenzenesulfonimide in CH2Cl2 to yield α-seleno-, α-thio-, or α-(phenyltelluro)alkylsulfonimides such as F3CCH(SePh)N(SO2Ph)2. Preliminary mechanistic studies indicate that a selenoimidate intermediate generated from diselenide and NFSI is involved for this transformation. The experimental part of the paper was very detailed, including the reaction process of 1,2-Diphenyldisulfane(cas: 882-33-7Recommanded Product: 1,2-Diphenyldisulfane)
1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.Ethers do have nonbonding electron pairs on their oxygen atoms, and they can form hydrogen bonds with other molecules (alcohols, amines, etc.) that have O―H or N―H bonds. The ability to form hydrogen bonds with other compounds makes ethers particularly good solvents for a wide variety of organic compounds and a surprisingly large number of inorganic compounds.Recommanded Product: 1,2-Diphenyldisulfane
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem