《Self-Assembled Multilayer Iron(0) Nanoparticle Catalyst for Ligand-Free Carbon-Carbon/Carbon-Nitrogen Bond-Forming Reactions》 was published in Organic Letters in 2020. These research results belong to Akiyama, Toshiki; Wada, Yuki; Yamada, Makito; Shio, Yasunori; Honma, Tetsuo; Shimoda, Shuhei; Tsuruta, Kazuki; Tamenori, Yusuke; Haneoka, Hitoshi; Suzuki, Takeyuki; Harada, Kazuo; Tsurugi, Hayato; Mashima, Kazushi; Hasegawa, Jun-ya; Sato, Yoshihiro; Arisawa, Mitsuhiro. Quality Control of 1-Iodo-2-methoxybenzene The article mentions the following:
Self-assembled multilayer iron(0) nanoparticles (NPs, 6-10 nm), namely, sulfur-modified Au-supported Fe(0) [SAFe(0)], were developed for ligand-free one-pot carbon-carbon/carbon-nitrogen bond-forming reactions. SAFe(0) was successfully prepared using a well-established metal-nanoparticle catalyst preparative protocol by simultaneous in situ metal NP and nanospace organization (PSSO) with 1,4-bis(trimethylsilyl)-1,4-dihydropyrazine (Si-DHP) as a strong reducing agent. SAFe(0) was easy to handle in air and could be recycled with a low iron-leaching rate in reaction cycles. In the experiment, the researchers used many compounds, for example, 1-Iodo-2-methoxybenzene(cas: 529-28-2Quality Control of 1-Iodo-2-methoxybenzene)
1-Iodo-2-methoxybenzene(cas: 529-28-2) is a useful synthetic intermediate. It can be used in the synthesis of piperidinyl diaminopyrimidines as cyclin-dependent kinase inhibitors with antitumor activity and polysubstituted benzofuran derivatives as novel inhibitors of parasitic growth.Quality Control of 1-Iodo-2-methoxybenzene
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