Wang, Jingyang; Wang, Yu; Ding, Guangni; Wu, Xiaoyu; Yang, Liqun; Fan, Sijie; Zhang, Zhaoguo; Xie, Xiaomin published an article in 2021. The article was titled 《Nickel-catalyzed deallylation of aryl allyl ethers with hydrosilanes》, and you may find the article in Tetrahedron Letters.Application In Synthesis of m-Methoxyphenol The information in the text is summarized as follows:
An efficient and mild catalytic deallylation method of aryl allyl ethers was developed, with com. available Ni(COD)2 as catalyst precursor, simple substituted bipyridine as ligand and air-stable hydrosilanes. The process was compatible with a variety of functional groups and the desired phenol products can be obtained with excellent yields and selectivity. Besides, by detection or isolation of key intermediates, mechanism studies confirm that the deallylation undergoes η3-allylnickel intermediate pathway. In the experiment, the researchers used m-Methoxyphenol(cas: 150-19-6Application In Synthesis of m-Methoxyphenol)
m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Application In Synthesis of m-Methoxyphenol
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem