Product Details of 101-70-2In 2019 ,《Quinoxaline based amines as blue-orange emitters: Effect of modulating donor system on optoelectrochemical and theoretical properties》 appeared in Dyes and Pigments. The author of the article were Kanekar, Deepali N.; Chacko, Sajeev; Kamble, Rajesh M.. The article conveys some information:
A series of eight novel donor-acceptor based quinoxaline-amine derivatives 2-9 were prepared by modulating donor species on quinoxaline core with Buchwald-Hartwig coupling amination reaction. The synthesized mols. were fully characterized and studied for impact of D-A interaction on optoelectrochem. properties of derivatives Absorption spectra of 2-9 display intramol. charge transfer (ICT) transitions in the range of 377-456 nm. Dyes 2-9 show pos. solvatochromism in emission and emit in blue-orange region with emission maxima 472-592 nm on excitation at their resp. ICT maxima in toluene, chloroform, DCM and neat solid film. Herein, dyes 2, 3 and 7 which possess intense emission in solid state were further studied for Aggregation Induced Emission (AIE) effect. The HOMO and LUMO energy level for compound 2-9 obtained by CV were found in the range of -5.23 to -5.83 eV and -3.55 to -3.74 eV. Theor. studies of mols. were also carried out by using TD-DFT calculations The comparable HOMO and LUMO energy level of 2-9 with reported ambipolar materials and efficient solid state emission make synthesized compounds potential candidate for solid state emissive, ambipolar materials in organic electronics. The experimental part of the paper was very detailed, including the reaction process of Bis(4-methoxyphenyl)amine(cas: 101-70-2Product Details of 101-70-2)
Bis(4-methoxyphenyl)amine(cas: 101-70-2) is a diphenylamine derivative used as a chemical additive for cured rubber.Bis(4-methoxyphenyl)amine is highly toxic and may potentially induce chromosome abberation.Product Details of 101-70-2
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