《The efficient synthesis of D-xylulose and formal synthesis of Syringolide 1》 was written by Kalagara, Sudhakar; Orozco, Gabriel; Mito, Shizue. Recommanded Product: 60656-87-3This research focused onxylulose stereoselective hydroxylation hydroxyacetone ethylene glycol syringolide Wittig. The article conveys some information:
Wittig reaction and asym. dihydroxylation were used as the key steps in the synthesis of D-xylulose, a com. available but costly carbohydrate. The effects of protecting groups and reactions conditions on asym. dihydroxylation are demonstrated. Optically pure D-xylulose was obtained after 4-6 steps from readily available hydroxyacetone and ethylene glycol. The method also involves some other valuable intermediates along the synthesis. Those intermediates were applied in the formal synthesis of Syringolides. A key precursor butenolide to Syringolide 1, the first non-protein specific elicitors of plant hypersensitive response, was obtained after 3 steps from the intermediate (8-10 steps from hydroxyacetone and ethylene glycol). In the experiment, the researchers used many compounds, for example, 2-(Benzyloxy)acetaldehyde(cas: 60656-87-3Recommanded Product: 60656-87-3)
2-(Benzyloxy)acetaldehyde(cas: 60656-87-3) is a non-natural aldehyde. It undergoes enantioselective Mukaiyama aldol reaction with silylketene acetal nucleophiles in the presence of C2-symmetric bis(oxazolinyl)pyridine Cu(II) complex (catalyst).Recommanded Product: 60656-87-3
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem