The author of 《Iodine(III)-Catalyzed Electrophilic Nitration of Phenols via Non-Bronsted Acidic NO2+ Generation》 were Juarez-Ornelas, Kevin A.; Jimenez-Halla, J. Oscar C.; Kato, Terumasa; Solorio-Alvarado, Cesar R.; Maruoka, Keiji. And the article was published in Organic Letters in 2019. Related Products of 150-19-6 The author mentioned the following in the article:
The first catalytic procedure for the electrophilic nitration of phenols was developed using iodosylbenzene as an organocatalyst based on iodine(III) and aluminum nitrate as a nitro group source. This atom-economic protocol occurs under mild, non-Bronsted acidic and open-flask reaction conditions with a broad functional-group tolerance including several heterocycles. D. functional theory (DFT) calculations at the (SMD:MeCN)Mo8-HX/(LANLo8+f,6-311+G*) level indicated that the reaction proceeds through a cationic pathway that efficiently generates the NO2+ ion, which is the nitrating species under neutral conditions. After reading the article, we found that the author used m-Methoxyphenol(cas: 150-19-6Related Products of 150-19-6)
m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Related Products of 150-19-6
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem