《Palladium-catalyzed selective defluorinative sulfenylation for the synthesis of fluorovinylthioethers》 was written by He, Shi-Yu; Zhang, Xing-Guo. Formula: C12H10S2 And the article was included in Organic Chemistry Frontiers in 2020. The article conveys some information:
An efficient transformation of trifluoromethylated compounds to monofluoroalkenes RCH=C(F)SR1 [R = Ph, 4-MeC6H4, 3-FC6H4, etc.; R1 = Ph, Bn, 2-thienyl, etc.] was developed through Pd-catalyzed selective defluorinative sulfenylation. Variety of α-fluorovinylthioethers RCH=C(F)SR1 were prepared in good yields from α-trifluoromethylated benzyl bromides and odorless disulfides. In addition to this study using 1,2-Diphenyldisulfane, there are many other studies that have used 1,2-Diphenyldisulfane(cas: 882-33-7Formula: C12H10S2) was used in this study.
1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.Although ethers resist hydrolysis, they are cleaved by hydrobromic acid and hydroiodic acid. Hydrogen chloride cleaves ethers only slowly. Formula: C12H10S2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem