Bourque, Jeremy L.; Nanni, Robert A.; Biesinger, Mark C.; Baines, Kim M. published their research in Inorganic Chemistry in 2021. The article was titled 《Synthesis and Reactivity of Cationic Gallium(I) [12]Crown-4 Complexes》.Related Products of 33100-27-5 The article contains the following contents:
The synthesis and reactivity of a Ga(I) cationic complex using [12]crown-4 as a stabilizing ligand were explored. The synthesis of [Ga([12]crown-4)][GaCl4] was achieved in one step from com. available starting materials. Anion exchange was used to replace the reactive tetrachlorogallate anion for the perfluorophenylborate anion. [Ga([12]crown-4)][B(C6F5)4] was analyzed using XPS, which allowed for the classification of the Ga(I)-crown ether complex as electron-deficient. Reactions of the Ga(I)-crown ether complex with Cp*K and cryptand[2.2.2] demonstrated the facile synthesis of a known Ga(I) compound as well as the generation of new Ga(I) complexes, highlighting the use of the Ga(I)-crown ether complex as an effective starting material for new Ga(I) complexes. In addition to this study using 1,4,7,10,13-Pentaoxacyclopentadecane, there are many other studies that have used 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Related Products of 33100-27-5) was used in this study.
1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Related Products of 33100-27-5
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem