《Carbamates: A Directing Group for Selective C-H Amidation and Alkylation under Cp*Co(III) Catalysis》 was published in Organic Letters in 2020. These research results belong to Bera, Sourav Sekhar; Maji, Modhu Sudan. Quality Control of m-Methoxyphenol The article mentions the following:
The selective reactivity of carbamate and thiocarbamate toward alkylation and amidation corresponding alkyl-carbamates e.g., I and amidyl-thiocarbamates e.g., II to get was reported under stable, high-valent, cost-effective cobalt(III) catalysis. This method revealed the wide possibility of designing a different branch of synthetically challenging yet highly promising asym. catalysts based on BINOL and SPINOL scaffolds. Late-stage C-H functionalization of L-tyrosine and estrone was also achieved through this approach. The mechanistic study shows that a base-assisted internal electrophilic substitution mechanism is operative here. After reading the article, we found that the author used m-Methoxyphenol(cas: 150-19-6Quality Control of m-Methoxyphenol)
m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneQuality Control of m-Methoxyphenol
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem