Recommanded Product: 1,2-DiphenyldisulfaneIn 2019 ,《Biomimetic catalytic oxidative coupling of thiols using thiolate-bridged dinuclear metal complexes containing iron in water under mild conditions》 was published in Catalysis Science & Technology. The article was written by Zhang, Yahui; Yang, Dawei; Li, Ying; Zhao, Xiangyu; Wang, Baomin; Qu, Jingping. The article contains the following contents:
Thiolate-bridged heterobimetallic half-sandwich complexes [Cp’M1(μ-SCH2CH2SCH2CH2S)M2Cp*][X] (2-PF6, Cp’ = C5Me5, M1 = Ru, M2 = Fe; 4a-BPh4, Cp’ = C5Me5, M1 = Fe, M2 = Co; 4b-BPh4, Cp’ = C5HMe4, M1 = Fe, M2 = Co) were prepared as catalysts for aerial oxidative coupling of thiols into disulfides. A green and efficient approach to disulfides via oxidative coupling of thiols was developed by adopting a biomimetic thiolate-bridged iron-ruthenium complex as the catalyst. Using environmentally friendly oxygen as the oxidant, a wide range of thiols including biol. important mols. can be smoothly converted into corresponding disulfides in water. Notably, two potential intermediate species were successfully isolated and unambiguously characterized, which is essential to reveal the detailed mechanism of this transformation. This catalytic system represents a rare and desired heteronuclear bimetallic scaffold for understanding the biol. process of S-S bond formation from the viewpoint of bioinspired catalysis. In addition to this study using 1,2-Diphenyldisulfane, there are many other studies that have used 1,2-Diphenyldisulfane(cas: 882-33-7Recommanded Product: 1,2-Diphenyldisulfane) was used in this study.
1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers. Ethers lack the hydroxyl groups of alcohols. Without the strongly polarized O―H bond, ether molecules cannot engage in hydrogen bonding with each other. Recommanded Product: 1,2-Diphenyldisulfane
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem