Computed Properties of C12H10S2In 2019 ,《In situ Formation of RSCl/ArSeCl and Their Oxidative Coupling with Enaminone Derivatives Under Transition-metal Free Conditions》 was published in Advanced Synthesis & Catalysis. The article was written by Shang, Zhenhua; Chen, Qingyu; Xing, Linlin; Zhang, Yilin; Wait, Laura; Du, Yunfei. The article contains the following contents:
The reaction of diorganyl disulfides or diselenides RX2R (R = Ph, 4-chlorophenyl, 1,3-benzothiazol-2-yl, etc.; X = Se, S) with PhICl2 in DMF at room temperature led to the in situ formation of the reactive organosulfenyl chloride (RSCl) or selenyl chloride (RSeCl), which reacted with enaminone compounds (E)-R2NHC(R1)=CHR3 (R1 = Me, Ph, thiophen-2-yl, etc.; R2 = H, Ph, Bn; R3 = methoxycarbonyl, benzoyl, CN, N-phenylcarbamoyl; R1R3 = -C(O)(CH2)3-) to afford a series of α-thioenaminones/α-selenylenaminones (E)-R2NHC(R1)=C(R3)XR resp., including the bioactive inhibitor for Cdc25B and its analog, via the intermol. oxidative C(sp2)-S/Se cross coupling reactions under metal-free conditions. The results came from multiple reactions, including the reaction of 1,2-Diphenyldisulfane(cas: 882-33-7Computed Properties of C12H10S2)
1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.Computed Properties of C12H10S2Although ethers resist hydrolysis, they are cleaved by hydrobromic acid and hydroiodic acid. Hydrogen chloride cleaves ethers only slowly.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem