《Cp*Co(III)-Catalyzed o-Amidation of Benzaldehydes with Dioxazolones Using Transient Directing Group Strategy》 was published in Advanced Synthesis & Catalysis in 2020. These research results belong to Khan, Bhuttu; Dwivedi, Vikas; Sundararaju, Basker. Application of 135-02-4 The article mentions the following:
Transition metal-catalyzed ortho-selective C(sp2)-H amidation of weakly coordinating aldehydes remains limited to precious metals such as Ir, Rh, Ru, etc. Herein, a novel report on ortho-amidation of benzaldehydes employing user-friendly dioxazolones under cost-effective and air-stable Cp*Co(III) catalysis. This catalytic transformation involves transient directing group strategy to enhance the ligating capability of weakly chelating aldehydes.2-Methoxybenzaldehyde(cas: 135-02-4Application of 135-02-4) was used in this study.
2-Methoxybenzaldehyde(cas: 135-02-4) is used as a flavor agent in foods including nonalcoholic/alcoholic beverages, baked goods, chewing gum, confections, frozen dairy, fruit ices, hard/soft candy, instant coffee, tea, Jams, jellies, and milk products. It also has been used to obtain good enantioselectivities using Cu(OAc)(2)-bis(oxazolines) via hydrogen bonding in asymmetric Henry reaction.Application of 135-02-4
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