Synthetic Route of C7H7IOIn 2020 ,《Chemoselective Rhodium-Catalyzed Borylation of Bromoiodoarenes Under Mild Conditions》 appeared in Journal of Organic Chemistry. The author of the article were Varni, Anthony J.; Bautista, Michael V.; Noonan, Kevin J. T.. The article conveys some information:
A chemoselective rhodium-catalyzed borylation has been developed for the preparation of aryl boronate esters. The reaction proceeds under mild conditions with excellent selectivity for C-I bonds in bromoiodoarenes and exhibits broad functional group tolerance. This procedure can act as a complementary approach toward bifunctional arenes along with other metal-catalyzed borylations. Addnl., the reaction’s utility in the preparation of monomers for metal-catalyzed cross-coupling polymerization is demonstrated. The experimental part of the paper was very detailed, including the reaction process of 1-Iodo-2-methoxybenzene(cas: 529-28-2Synthetic Route of C7H7IO)
1-Iodo-2-methoxybenzene(cas: 529-28-2) participates in palladium catalyzed enantioselective Heck arylation of 2,3-dihydrofuran in the presence of chiral ionic liquids containing L-prolinate and L-lactate anions and non-chiral quaternary ammonium cations.Synthetic Route of C7H7IO
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem