Brown, Charles; Sikkel, Bernardus J.; Carvalho, Christopher F.; Sargent, Melvyn V. published their research in Journal of the Chemical Society on December 31 ,1982. The article was titled 《A new phenanthrene synthesis》.Safety of (3-Methoxy-2-methylphenyl)methanol The article contains the following contents:
Treatment of substituted (Z)-2-chlorostilbenes with activated Mg, prepared by reduction of MgCl2 with K in THF containing KI, gave phenanthrenes. E.g., treatment 2-ClC6H4CH:CHC6H4R-2 (R = H, OMe) with activated Mg in refluxing THF for 12 h gave phenanthrenes I (R = H, OMe) in 83 and 76% yield, resp. The reaction mechanism involves homolytic substitution. The experimental process involved the reaction of (3-Methoxy-2-methylphenyl)methanol(cas: 33797-34-1Safety of (3-Methoxy-2-methylphenyl)methanol)
(3-Methoxy-2-methylphenyl)methanol(cas: 33797-34-1) belongs to ethers. Ethers lack the hydroxyl groups of alcohols. Without the strongly polarized O―H bond, ether molecules cannot engage in hydrogen bonding with each other. Safety of (3-Methoxy-2-methylphenyl)methanol
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem