In 2019,Angewandte Chemie, International Edition included an article by Anthony, David; Lin, Qiao; Baudet, Judith; Diao, Tianning. Category: ethers-buliding-blocks. The article was titled 《Nickel-Catalyzed Asymmetric Reductive Diarylation of Vinylarenes》. The information in the text is summarized as follows:
A nickel-catalyzed asym. diarylation reaction of vinylarenes enabled the preparation of chiral α,α,β-triarylated ethane scaffolds, which existed in a number of biol. active mols. The use of reducing conditions with aryl bromides as coupling partners obviated the need for stoichiometric organometallic reagents and tolerated a broad range of functional groups. The application of an N-oxyl radical as a ligand to a nickel catalyst represented a novel approach to facilitate nickel-catalyzed cross-coupling reactions.1-Bromo-3-methoxybenzene(cas: 2398-37-0Category: ethers-buliding-blocks) was used in this study.
1-Bromo-3-methoxybenzene(cas: 2398-37-0) is a compound useful in organic synthesis and other chemical processes. It is an intermediate used for pharmaceuticals, perfumes and agrochemicals.Category: ethers-buliding-blocks
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem