Zhang, Ying; Gao, Huanjie; Guo, Jiabao; Zhang, Hao; Yao, Xiaoquan published the artcile< Selective electrochemical para-thiocyanation of aromatic amines under metal-, oxidant- and exogenous-electrolyte-free conditions>, Quality Control of 10541-78-3, the main research area is thiocyanato aromatic compound preparation green chem regioselective; aromatic amine ammonium thiocyanate electrochem oxidative thiocyanation.
An electrochem. oxidative para-C-H-thiocyanation of aromatic amines RN(R1)R2 [R = Ph, naphthalen-1-yl, 2-methylphenyl, etc.; R1 = H, Me, Et, n-Pr, Ph; R2 = Me, Et, Ph, etc.; R1R2 = -(CH2)4-, -(CH2)5-, -(CH2)2O(CH2)2-] has been developed to construct thiocyanato aromatic compounds ;R3N(R1)R2 (R3 = 4-(cyanosulfanyl)benzen-1-yl, 4-(cyanosulfanyl)-3,5-dimethylbenzen-1-yl, 4-(cyanosulfanyl)naphthalen-1-yl, etc.) under metal-, oxidant-, and exogenous-electrolyte-free conditions in an undivided cell. The transformation is compatible with a range of primary, secondary, and tertiary amines and shows good functional group tolerance. This approach provides an economical and environmentally benign way for para-thiocyanation of aromatic amines.
Chemical Communications (Cambridge, United Kingdom) published new progress about Aromatic amines Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 10541-78-3 belongs to class ethers-buliding-blocks, and the molecular formula is C8H11NO, Quality Control of 10541-78-3.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem