Rodrigues, Fabio M. S.; Kucmierczyk, Peter K.; Pineiro, Marta; Jackstell, Ralf; Franke, Robert; Pereira, Mariette M.; Beller, Matthias published the artcile< Dual Rh-Ru Catalysts for Reductive Hydroformylation of Olefins to Alcohols>, SDS of cas: 52244-70-9, the main research area is alc preparation regioselective chemoselective; olefin reductive hydroformylation rhodium ruthenium catalyst; alcohols; homogeneous catalysis; rhodium; ruthenium; tandem reactions.
An active and selective dual catalytic system to promote domino hydroformylation-reduction reactions is described. Apart from terminal, di- and trisubstituted olefins, for the first time the less active internal C-C double bond of tetrasubstituted alkenes can also be utilized. As an example, 2,3-dimethylbut-2-ene is converted into the corresponding n-alc. with high yield (90 %) as well as regio- and chemoselectivity (>97 %). Key for this development is the use of a combination of Rh complexes with bulky monophosphite ligands and the Ru-based Shvo’s complex. A variety of aromatic and aliphatic alkenes can be directly used to obtain mainly linear alcs.
ChemSusChem published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, SDS of cas: 52244-70-9.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem