Nagasawa, Shota; Sasano, Yusuke; Iwabuchi, Yoshiharu published the artcile< Catalytic Oxygenative Allylic Transposition of Alkenes into Enones with an Azaadamantane-Type Oxoammonium Salt Catalyst>, Category: ethers-buliding-blocks, the main research area is allylic transposition oxygenative alkene azaadamantane type oxoammonium salt catalyst; enone preparation catalytic oxygenative allylic transposition alkene; alkenes; enones; organocatalysis; oxygenation; synthetic methods.
The first catalytic oxygenative allylic transposition of unactivated alkenes, e.g., Me2C:CH2(CH2)3OCOPh, into enones, e.g., H2C:C(Me)CO(CH2)3OCOPh, has been developed using an oxoammonium salt, azaadamantane I, as the catalyst. This reaction converts various tri- and trans-disubstituted alkenes into their corresponding enones with transposition of their double bonds at ambient temperature in good yields. The use of a less-hindered azaadamantane-type oxoammonium salt as the catalyst and a combination of two distinct stoichiometric oxidants, namely, iodobenzene diacetate and magnesium monoperoxyphthalate hexahydrate (MMPP·6H2O) are essential to facilitate the enone formation efficiently.
Chemistry – A European Journal published new progress about Alkenes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, Category: ethers-buliding-blocks.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem