Liu, Yu; Cornella, Josep; Martin, Ruben published the artcile< Ni-Catalyzed Carboxylation of Unactivated Primary Alkyl Bromides and Sulfonates with CO2>, Application of C11H16O2, the main research area is nickel catalyzed carboxylation primary alkyl bromide sulfonate carbon dioxide; carboxylic acid synthesis.
A Ni-catalyzed carboxylation of unactivated primary alkyl bromides and sulfonates with CO2 at atm. pressure is described. The method is characterized by its mild conditions and remarkably wide scope without the need for air- or moisture-sensitive reagents, which make it a user-friendly and operationally simple protocol en route to carboxylic acids. Thus, e.g., reductive carboxylation 1-bromo-6-(4-methoxyphenyl)hexane using NiCl2.glyme, 2,9-diethyl-1,10-phenanthroline ligand, Mn as reducing agent and CO2 afforded 7-(4-methoxyphenyl)heptanoic acid in 76% isolated yield.
Journal of the American Chemical Society published new progress about Bromoalkanes Role: RCT (Reactant), RACT (Reactant or Reagent) (primary). 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, Application of C11H16O2.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem