Kende, Andrew S’s team published research in Tetrahedron Letters in 1986 | 52244-70-9

Tetrahedron Letters published new progress about Cycloaddition reaction, intramolecular. 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, Electric Literature of 52244-70-9.

Kende, Andrew S.; Koch, Kevin published the artcile< Intramolecular radical cyclization of phenolic nitronates. Facile synthesis of annelated tropone and tropolone derivatives>, Electric Literature of 52244-70-9, the main research area is nitrophenolate electron transfer cyclization; spirocyclic nitro dienone preparation rearrangement; bicyclic tropone.

Treating p-HOC6H4(CH2)nNO2 (n = 4, 5) or 4,3-HO(MeO)C6H3(CH2)4NO2 with aqueous KOH followed by K3Fe(CN)6 gives spirocyclic nitrodienones I (X = CH2, CH2CH2; R = H, OMe), which rearrange to bicyclic tropones II (same X, R).

Tetrahedron Letters published new progress about Cycloaddition reaction, intramolecular. 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, Electric Literature of 52244-70-9.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem