Synthetic Route of C10H20O5In 2021 ,《Controlling the unpaired electron by electrostatic attraction in the solid state》 appeared in Chemical Communications (Cambridge, United Kingdom). The author of the article were Cui, Haiyan; Wang, Liting; Ruan, Huapeng; Liu, Min; Feng, Zhongtao; Wang, Jie; Zhao, Yue; Wang, Xinping. The article conveys some information:
One-electron reduction of 2,7-tBu2-pyrene-4,5,9,10-tetraone (1) with potassium afforded two monoradicals 1K(cryp) and 1K(18c6), a radical tetramer [1K(15c5)]4 and a radical polymer (1K)2n. Using 1K(cryp) and 1K(18c6), the authors demonstrated large spin d. modulation of an organic radical anion in the solid state by electrostatic attraction, without alternation of the mol. skeletons. In the experiment, the researchers used many compounds, for example, 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Synthetic Route of C10H20O5)
1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Synthetic Route of C10H20O5
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem