Application In Synthesis of 3-Methoxyphenylboronic acidIn 2020 ,《Nickel-catalyzed regio- and diastereoselective hydroarylative and hydroalkenylative cyclization of 1,6-dienes》 was published in Chemical Communications (Cambridge, United Kingdom). The article was written by Xu, Zhengshuai; Tang, Yitian; Shen, Chaoren; Zhang, Hongru; Gan, Yuxin; Ji, Xiaolei; Tian, Xinxin; Dong, Kaiwu. The article contains the following contents:
An unprecedented nickel-catalyzed hydroarylative and hydroalkenylative cyclization of unsym. substituted 1,6-dienes with organoboronic acid was developed by using MeOH as the hydrogen source and employing com. available Ni(η2-1,5-cyclooctadiene)2 as the catalyst. A series of biol. interesting cyclic products I [X = O, NTs, C(CO2Et)2; R1 = H, Ph, 1-naphthyl, etc.; R2 = CH:CHCH2CH2CH3, Ph, 4-FC6H4, etc.] were afforded in moderate to excellent yields with high regio- and diastereoselectivities. In the experiment, the researchers used 3-Methoxyphenylboronic acid(cas: 10365-98-7Application In Synthesis of 3-Methoxyphenylboronic acid)
3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Application In Synthesis of 3-Methoxyphenylboronic acid
Referemce:
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Ether | (C2H5)2O – PubChem