Huang, Chen; Feng, Jie; Ma, Rui; Fang, Shuaishuai; Lu, Tao; Tang, Weifang; Du, Ding; Gao, Jian published the artcile< Redox-Neutral Borylation of Aryl Sulfonium Salts via C-S Activation Enabled by Light>, Computed Properties of 190788-60-4, the main research area is aryl sulfonium salt preparation photochem redox neutral borylation pinacolatodiboron; arylboronate ester preparation; methyl aryl thioether methylation methyl triflate.
Reported here is a novel photoinduced strategy for the borylation of aryl sulfonium salts using bis(pinacolato)diboron as the B source. This method exploits redox-neutral aryl sulfoniums to gain access to aryl radicals via C-S bond activation upon photoexcitation under transition-metal-free conditions. Therefore, it grants access to diverse arylboronate esters with good performance from easily available aryl sulfoniums accompanied by mild conditions, operational simplicity, and easy scalability.
Organic Letters published new progress about Boranes Role: SPN (Synthetic Preparation), PREP (Preparation) (arylboronate esters). 190788-60-4 belongs to class ethers-buliding-blocks, and the molecular formula is C13H19BO3, Computed Properties of 190788-60-4.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem