Zhao, Xin; Yang, Fang; Zou, Shao-Yu; Zhou, Qian-Qian; Chen, Zi-Sheng; Ji, Kegong published the artcile< Cu-Catalyzed Intermolecular γ-Site C-H Amination of Cyclohexenone Derivatives: The Benefit of Bifunctional Ligands>, Formula: C8H11NO, the main research area is aniline cyclohexenone copper catalyst regioselective amination green chem; amino alc preparation antibacterial antioxidant; cyclohexadienyl oxy silyl ether aniline copper regioselective diastereoselective amination; aminocyclohexenone preparation green chem.
Utilizing 1,10-phenanthroline-type bifunctional ligands, an efficient Cu-catalyzed intermol. site-selective remote C-H amination using cyclohexenone derivatives and anilines was realized. The amide group installed on the bifunctional ligand played a key role in stabilizing the N-centered radical generated in-situ to realize C-N-directed formation. Meanwhile, a useful catalytic system for site-selective intermol. remote γ-C-H amination to p-aminophenols and γ-aminated enones was established. This economical and practical approach using oxygen as the terminal oxidant was mild and environmentally friendly.
ACS Catalysis published new progress about Amination catalysts (stereoselective, regioselective). 10541-78-3 belongs to class ethers-buliding-blocks, and the molecular formula is C8H11NO, Formula: C8H11NO.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem