Verma, Piyush Kumar’s team published research in Organic Letters in 2020-02-21 | 6482-24-2

Organic Letters published new progress about Boronic acids, esters Role: SPN (Synthetic Preparation), PREP (Preparation) (alkyl boronic esters). 6482-24-2 belongs to class ethers-buliding-blocks, and the molecular formula is C3H7BrO, Recommanded Product: 1-Bromo-2-methoxyethane.

Verma, Piyush Kumar; Prasad, K. Sujit; Varghese, Dominic; Geetharani, K. published the artcile< Cobalt(I)-Catalyzed Borylation of Unactivated Alkyl Bromides and Chlorides>, Recommanded Product: 1-Bromo-2-methoxyethane, the main research area is cobalt catalyzed borylation unactivated alkyl bromide chloride diboron reagent; alkyl boronic ester preparation.

A Co-complex-catalyzed borylation of a wide range of alkyl halides with a diboron reagent (B2pin2 or B2neop2) was developed under mild reaction conditions, demonstrating the 1st Co-mediated cross-coupling with alkyl electrophiles. This protocol allows alkyl boronic esters to be accessed from alkyl halides, including alkyl chlorides, which were used rarely as coupling partners. Mechanistic studies reveal the possible involvement of an alkyl radical intermediate in this Co-mediated catalytic cycle.

Organic Letters published new progress about Boronic acids, esters Role: SPN (Synthetic Preparation), PREP (Preparation) (alkyl boronic esters). 6482-24-2 belongs to class ethers-buliding-blocks, and the molecular formula is C3H7BrO, Recommanded Product: 1-Bromo-2-methoxyethane.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem