Jue, Zhaofan; Huang, Yahao; Qian, Jiahui; Hu, Peng published the artcile< Visible Light-Induced Unactivated δ-C(sp3)-H Amination of Alcohols Catalyzed by Iron>, COA of Formula: C11H16O2, the main research area is primary secondary tertiary alc amination visible light iron; C−H activation; amination; hydrogen transfer; iron; photocatalysis.
An iron-catalyzed remote C(sp3)-H amination of alcs. through 1,5-hydrogen atom transfer is developed. This protocol provides a method to generate δ-C(sp3)-N bonds from primary, secondary, and tertiary alcs. under mild conditions. A wide substrate scope and a good functional group tolerance are presented. Mechanistic studies show that a LMCT course of an Fe-OR species and a chlorine radical-induced hydrogen abstraction of an alc. are possible to generate the alkoxy radical intermediate.
ChemSusChem published new progress about Amination. 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, COA of Formula: C11H16O2.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem