Bam, Radha; Pollatos, Alexandros S.; Moser, Austin J.; West, Julian G. published the artcile< Mild olefin formation via bio-inspired vitamin B12 photocatalysis>, Recommanded Product: 4-(4-Methoxyphenyl)-1-butanol, the main research area is haloalkane cobalamin catalyst regioselective photochem dehydrohalogenation; alkene preparation; alkyl sulfonate cobalamin catalyst regioselective photochem olefination; olefin preparation.
A light-driven B12-based catalytic system that leverages this reactivity to convert alkyl electrophiles to olefins under incredibly mild conditions using only earth abundant elements was reported. Further, this process exhibited a high level of regioselectivity, producing terminal olefins in moderate to excellent yield and exceptional selectivity. Finally, it was able to access a hitherto-unknown transformation, remote elimination, using two cobalt catalysts in tandem to produce subterminal olefins with excellent regioselectivity. Together, vitamin B12 to be a powerful platform for developing mild olefin-forming reactions was showed.
Chemical Science published new progress about Alkanesulfonates Role: RCT (Reactant), RACT (Reactant or Reagent). 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, Recommanded Product: 4-(4-Methoxyphenyl)-1-butanol.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem