Baker, Robert W.; Liu, Song; Sargent, Melvyn V.; Skelton, Brian W.; White, Allan H. published the artcile< Regioselectivity in the lithiation of 1,3-disubstituted arenes>, Application In Synthesis of 17100-64-0, the main research area is regioselectivity lithiation arene; naphthalenecarboxaldehyde tetramethoxy lithiation regiochem; naphthalenemethanol tetramethoxy lithiation regiochem; methoxybenzyl alc lithiation regiochem.
The regioselectivity of the lithiation of 1,4,5,8-tetramethoxynaphthalene-2-carbaldehyde with BuLi or PhLi in the presence of N,N,N’-trimethylethylenediamine and the subsequent bromination of the lithiated species so generated with 1,2-dibromotetrafluoroethane were investigated. Similar investigations with BuLi as base in the presence of N,N,N’,N’-tetramethylethylenediamine or KOCMe3 were carried out on 1,4,5,8-tetramethoxynaphthalene-2-methanol. These studies were extended to 1,5,8-trimethoxynaphthalene-3-methanol, (3-methoxybenzene)methanol and (3,5-dimethoxybenzene)methanol. The X-ray crystal structure of 6-bromo-1,4,5,8-tetramethoxynaphthalene-2-methanol is described.
Australian Journal of Chemistry published new progress about Aromatic hydrocarbons Role: RCT (Reactant), RACT (Reactant or Reagent). 17100-64-0 belongs to class ethers-buliding-blocks, and the molecular formula is C8H9BrO2, Application In Synthesis of 17100-64-0.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem