Albiniak, Philip A.; Amisial, Shawn M.; Dudley, Gregory B.; Hernandez, Joseph P.; House, Sarah E.; Matthews, Margaret E.; Nwoye, Ernest O.; Reilly, Maureen K.; Tlais, Sami F. published the artcile< Stable oxypyridinium triflate (OPT) salts for the synthesis of halobenzyl ethers>, HPLC of Formula: 52244-70-9, the main research area is pyridinium triflate halobenzyloxy preparation benzylation alc; ether halobenzyl preparation.
A collection of new 2-arylmethoxy-1-methylpyridinium triflate reagents (aryl = 4-BrC6H4, 4-ClC6H4, 4-IC6H4, 2-BrC6H4) for the synthesis of halobenzyl ethers ROCH2Ar [R = Ph(CH2)3, 4-MeOC6H4(CH2)4, 1-adamantyl, (R)-MeO2CCHMeCH2, 5α-cholester-3β-yl] from alcs. ROH under mix-and-heat conditions is described. The reagents are stable organic salts that can be stored indefinitely and handled without special precautions, making them attractive for general use in organic synthesis. Halobenzylation of representative alcs. occurs in good to excellent yields.
Synthetic Communications published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, HPLC of Formula: 52244-70-9.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem