Tang, Huali;Huang, Bin;Xie, Xiujun;Yan, Tao;Cai, Mingzhong published 《Synthesis and properties of novel soluble fluorinated aromatic polyamides containing 4-benzoyl-2,3,5,6-tetrafluorophenoxy pendant groups》 in 2018. The article was appeared in 《Journal of Polymer Research》. They have made some progress in their research.Quality Control of 3-(4-Aminophenoxy)aniline The article mentions the following:
A new diaroyl chloride monomer, 5-(4-benzoyl-2,3,5,6-tetrafluorophenoxy)isophthaloyl dichloride (BTFPIPC), was prepared in a three-step synthesis. Six novel aromatic polyamides containing 4-benzoyl-2,3,5,6-tetrafluorophenoxy pendant groups were synthesized by low temperature polycondensation of BTFPIPC with six aromatic diamines in N,N-dimethylacetamide (DMAc). All these new polymers are amorphous and readily soluble in various dipolar solvents such as DMAc, N-methyl-2-pyrrolidinone (NMP), N,N-dimethylformamide (DMF), and DMSO (DMSO) at room temperature These polymers showed glass transition temperatures between 212 and 243 °C and 5% weight loss temperatures ranging from 439 °C to 456 °C. These polyamides could be cast into transparent, flexible and strong films from DMAc solution with tensile strengths of 73.5-85.4 MPa, tensile moduli of 2.06-2.72 GPa, and elongations at break of 6.4-9.3%. These new polyamide films exhibited low dielec. constants of 3.26-3.57 (1 MHz), lower water uptakes in the range of 1.27-2.28%, and excellent transparency with an UV-visible absorption cut-off wavelength in the 326-373 nm range. Primary characterization of these new polyamides shows that they might serve as new candidates for processable high-performance polymeric materials.3-(4-Aminophenoxy)aniline (cas: 2657-87-6) were involved in the experimental procedure.
3-(4-Aminophenoxy)aniline is one of ethers-buliding-blocks. Ethers lack the hydroxyl groups of alcohols. Without the strongly polarized O―H bond, ether molecules cannot engage in hydrogen bonding with each other. Quality Control of 3-(4-Aminophenoxy)anilineEthers do have nonbonding electron pairs on their oxygen atoms, however, and they can form hydrogen bonds with other molecules (alcohols, amines, etc.) that have O―H or N―H bonds.
Reference:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem