Ngai, Courtney;Sanchez-Marsetti, Colomba M.;Harman, W. Hill;Hooley, Richard J. published 《Supramolecular Catalysis of the oxa-Pictet-Spengler Reaction with an Endohedrally Functionalized Self-Assembled Cage Complex》. The research results were published in《Angewandte Chemie, International Edition》 in 2020.Application In Synthesis of Dimethoxydiphenylmethane The article conveys some information:
An endohedrally functionalized self-assembled Fe4L6 cage complex can catalyze oxa-Pictet-Spengler cyclizations of tryptophols and various aldehyde derivatives, showing strong rate accelerations and size-selectivity. Selective mol. recognition of substrates controls the reactivity, and the cage is capable of binding and activating multiple different species along the multistep reaction pathway. The combination of a functionalized active site, size-selective reactivity, and multistep activation, all from a single host mol., illustrates the biomimetic nature of the catalysis. To complete the study, the researchers used Dimethoxydiphenylmethane (cas: 2235-01-0) .
For example, the most common synthesis of ethers involves the attack of an alkoxide ion on an alkyl halide. This method is called Williamson ether synthesis.Application In Synthesis of Dimethoxydiphenylmethane
Reference:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem