Quality Control of Diphenyl oxide. Verevkin, SP; Siewert, R; Emel’yanenko, VN; Bara, JE; Cao, HD; Pimerzin, AA in [Verevkin, Sergey P.; Siewert, Riko] Univ Rostock, Competence Ctr CALOR, Dept Phys Chem, D-18059 Rostock, Germany; [Verevkin, Sergey P.; Siewert, Riko] Univ Rostock, Competence Ctr CALOR, Fac Interdisciplinary Res, D-18059 Rostock, Germany; [Verevkin, Sergey P.; Emel’yanenko, Vladimir N.; Pimerzin, Andrey A.] Samara State Tech Univ, Chem Dept, Samara 443100, Russia; [Bara, Jason E.] Univ Alabama, Dept Chem & Biol Engn, Tuscaloosa, AL 35487 USA; [Cao, Hongda] Univ Alabama, Dept Chem & Biochem, Tuscaloosa, AL 35487 USA published Diphenyl Ether Derivatives as Potential Liquid Organic Hydrogen Carriers: Thermochemical and Computational Study in 2020.0, Cited 33.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.
The liquid organic hydrogen carriers (LOHCs) are promising materials for hydrogen storage. The standard molar enthalpies of formation, Delta H-f(m)o (liq/cr) of diphenyl ether substituted with methyl, methoxy, and hydroxyl substituents were measured by the high-precision combustion calorimetry. Enthalpies of vaporization/sublimation Delta(g)(l,cr) H-o(m) (298.15 K) of these compounds were obtained by the transpiration method. Enthalpies of fusion of 2- and 4-hydroxy-diphenyl ether were measured by differential scanning calorimeter. Gas-phase enthalpies of formation Delta H-f(o)m (g, 298.15 K) of substituted diphenyl ethers calculated by the G4 method were in an excellent agreement with the experimental results. Enthalpies of the hydrogenation/dehydrogenation reactions of diphenyl ether derivatives were estimated and compared with the data available for other potential LOHC. A set of thermodynamic properties of diphenyl ether derivatives of benchmark quality was recommended for thermochemical calculations. Equilibrium temperatures of hydrogenation/dehydrogenation processes were calculated and compared with those of benzene derivatives. Because of their high hydrogen storage capacity, as well as very low volatility, these compounds could be considered as seminal candidates for LOHC.
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Reference:
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,Ether | (C2H5)2O – PubChem