Recently I am researching about C-O BONDS; TRANSFER HYDROGENOLYTIC CLEAVAGE; AROMATIC ETHER BONDS; BENZYL PHENYL ETHER; MODEL COMPOUNDS; RU CATALYST; METAL; HYDRODEOXYGENATION; EFFICIENT; ACID, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21878288, 21690080, 21690083, 21721004]; DNL Cooperation Fund CAS [DNL180302]; Strategic Priority Research Program of the Chinese Academy of SciencesChinese Academy of Sciences [XDB17020100]; National Key R&D Program of China [2016YFA0202801, 2018YFB1501402]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Li, XX; Zhang, B; Pan, XL; Ji, JW; Ren, YJ; Wang, H; Ji, N; Liu, QY; Li, CZ. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide. Name: Diphenyl oxide
The direct transformation of lignin into fuels and chemicals remains a huge challenge because of the recalcitrant and complicated structure of lignin. In this study, rhenium oxide-modified iridium supported on SiO2 (Ir-ReOx/SiO2) is employed for the one-pot conversion of various lignin model compounds and lignin feedstocks into naphthenes. Up to 100 % yield of cyclohexane from model compounds and 44.3 % yield of naphthenes from lignin feedstocks are achieved. 2 D HSQC NMR spectroscopy before and after the reaction confirms the activity of Ir-ReOx/SiO2 in the cleavage of the C-O bonds and hydrodeoxygenation of the depolymerized products. H-2 temperature-programmed reduction, temperature-programmed desorption of NH3, IR spectroscopy of pyridine adsorption, X-ray photoelectron spectroscopy, X-ray absorption fine structure analysis, and control experiments reveal that a synergistic effect between Ir and ReOx in Ir-ReOx/SiO2 plays a crucial role in the high performance; ReOx is mainly responsible for the cleavage of C-O bonds, whereas Ir is responsible for hydrodeoxygenation and saturation of the benzene rings. This methodology opens up an energy-efficient route for the direct conversion of lignin into valuable naphthenes.
Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.. Name: Diphenyl oxide
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem