An article alpha-Diimine-Niobium Complex-Catalyzed Deoxychlorination of Benzyl Ethers with Silicon Tetrachloride WOS:000489676400043 published article about O-ACYLATIVE CLEAVAGE; BOND; ACTIVATION; CHLORIDE; LIGANDS; REAGENT; HALIDES in [Parker, Bernard F.; Hosoya, Hiromu; Tsurugi, Hayato; Mashima, Kazushi] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan; [Parker, Bernard F.; Arnold, John] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA in 2019, Cited 34. Category: ethers-buliding-blocks. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4
alpha-Diimine niobium complexes serve as catalysts for deoxygenation of benzyl ethers by silicon tetrachloride (SiCl4) to cleanly give two equivalents of the corresponding benzyl chlorides, where SiCl4 has the dual function of oxygen scavenger and chloride source with the formation of a silyl ether or silica as the only byproduct. The reaction mechanism has two successive trans-etherification steps that are mediated by the niobium catalyst, first forming one equivalent of benzyl chloride along with the corresponding silyl ether intermediate that undergoes the same reaction pathway to give the second equivalent of benzyl chloride and silyl ether.
Category: ethers-buliding-blocks. Welcome to talk about 103-50-4, If you have any questions, you can contact Parker, BF; Hosoya, H; Arnold, J; Tsurugi, H; Mashima, K or send Email.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem