Month: December 2021

I found the field of Chemistry; Science & Technology – Other Topics very interesting. Saw the article Highly Efficient Cleavage of Ether Bonds in Lignin Models by Transfer Hydrogenolysis over Dual-Functional Ruthenium/Montmorillonite published in 2020.0. Name: Diphenyl oxide, Reprint Addresses Xue, ZM (corresponding author), Beijing Forestry Univ, Coll Mat Sci & Technol, Beijing Key Lab Lignocellulos Chem, Beijing 100083, Peoples R China.; Mu, TC (corresponding author), Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

Cleavage of ether bonds is a crucial but challenging step for lignin valorization. To efficiently realize this transformation, the development of robust catalysts or catalytic systems is required. In this study, montmorillonite (MMT)-supported Ru (denoted as Ru/MMT) is fabricated as a dual-functional heterogeneous catalyst to cleave various types of ether bonds through transfer hydrogenolysis without using any additional acids or bases. The prepared Ru/MMT material is found to efficiently catalyze the cleavage of various lignin models and lignin-derived phenols; cyclohexanes (fuels) and cyclohexanols (key intermediates) are the main products. The synergistic effect between electron-enriched Ru and the acidic sites on MMT contributes to the excellent performance of Ru/MMT. Systematic studies reveal that the reaction proceeds through two possible reaction pathways, including the direct cleavage of ether bonds and the formation of intermediates with one hydrogenated benzene ring, for all examined types of ether bonds, namely, 4-O-5, alpha-O-4, and beta-O-4.

Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.. Name: Diphenyl oxide

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

In 2020 NANOMATERIALS-BASEL published article about IRON-OXIDE NANOCUBES; FLUID HYPERTHERMIA; PROTON THERAPY; RADIATION; RADIOTHERAPY; COMBINATION; CELLS; TUMOR; MFH; CHEMOTHERAPY in [Brero, Francesca; Avolio, Matteo; Corti, Maurizio; Mariani, Manuel; Lascialfari, Alessandro] Univ Pavia, Dipartimento Fis, I-27100 Pavia, Italy; [Brero, Francesca; Avolio, Matteo; Corti, Maurizio; Mariani, Manuel; Lascialfari, Alessandro] Univ Pavia, Ist Nazl Fis Nucl, I-27100 Pavia, Italy; [Albino, Martin; Guerrini, Andrea; Innocenti, Claudia; Sangregorio, Claudio] Univ Firenze, Dipartimento Chim, I-50019 Sesto Fiorentino, FI, Italy; [Albino, Martin; Guerrini, Andrea; Innocenti, Claudia; Sangregorio, Claudio] INSTM, I-50019 Sesto Fiorentino, FI, Italy; [Antoccia, Antonio; Berardinelli, Francesco] Univ Roma Tre, Dipartimento Sci, I-00146 Rome, Italy; [Antoccia, Antonio; Berardinelli, Francesco] Univ Roma Tre, Ist Nazl Fis Nucl, I-00146 Rome, Italy; [Arosio, Paolo; Bettega, Daniela; Calzolari, Paola; Gallo, Salvatore; Lenardi, Cristina; Locarno, Silvia; Marchesini, Renato; Orsini, Francesco; Veronese, Ivan] Univ Milan, Dipartimento Fis, I-20133 Milan, Italy; [Arosio, Paolo; Bettega, Daniela; Calzolari, Paola; Gallo, Salvatore; Lenardi, Cristina; Locarno, Silvia; Marchesini, Renato; Orsini, Francesco; Veronese, Ivan] Univ Milan, Ist Nazl Fis Nucl, I-20133 Milan, Italy; [Ciocca, Mario; Facoetti, Angelica] Fdn CNAO, I-27100 Pavia, Italy; [Groppi, Flavia; Manenti, Simone] Univ Milan, Dipartimento Fis, I-20090 Segrate, MI, Italy; [Groppi, Flavia; Manenti, Simone] Ist Nazl Fis Nucl, Lab LASA, I-20090 Segrate, MI, Italy; [Innocenti, Claudia; Sangregorio, Claudio] ICCOM CNR, I-50019 Sesto Fiorentino, FI, Italy; [Lenardi, Cristina] Ctr Interdisciplinare Mat & Interfacce Nanostrutt, CIMaINa, I-20133 Milan, Italy; [Pignoli, Emanuele] Fdn IRCSS Ist Nazl Tumori, I-20133 Milan, Italy; [Sangregorio, Claudio] Ist Nazl Fis Nucl, Sez Firenze, I-50019 Sesto Fiorentino, FI, Italy in 2020, Cited 76. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. HPLC of Formula: C14H14O

A combination of carbon ions/photons irradiation and hyperthermia as a novel therapeutic approach for the in-vitro treatment of pancreatic cancer BxPC3 cells is presented. The radiation doses used are 0-2 Gy for carbon ions and 0-7 Gy for 6 MV photons. Hyperthermia is realized via a standard heating bath, assisted by magnetic fluid hyperthermia (MFH) that utilizes magnetic nanoparticles (MNPs) exposed to an alternating magnetic field of amplitude 19.5 mTesla and frequency 109.8 kHz. Starting from 37 degrees C, the temperature is gradually increased and the sample is kept at 42 degrees C for 30 min. For MFH, MNPs with a mean diameter of 19 nm and specific absorption rate of 110 +/- 30 W/g(Fe3)o(4) coated with a biocompatible ligand to ensure stability in physiological media are used. Irradiation diminishes the clonogenic survival at an extent that depends on the radiation type, and its decrease is amplified both by the MNPs cellular uptake and the hyperthermia protocol. Significant increases in DNA double-strand breaks at 6 h are observed in samples exposed to MNP uptake, treated with 0.75 Gy carbon-ion irradiation and hyperthermia. The proposed experimental protocol, based on the combination of hadron irradiation and hyperthermia, represents a first step towards an innovative clinical option for pancreatic cancer.

Welcome to talk about 103-50-4, If you have any questions, you can contact Brero, F; Albino, M; Antoccia, A; Arosio, P; Avolio, M; Berardinelli, F; Bettega, D; Calzolari, P; Ciocca, M; Corti, M; Facoetti, A; Gallo, S; Groppi, F; Guerrini, A; Innocenti, C; Lenardi, C; Locarno, S; Manenti, S; Marchesini, R; Mariani, M; Orsini, F; Pignoli, E; Sangregorio, C; Veronese, I; Lascialfari, A or send Email.. HPLC of Formula: C14H14O

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Theoretical Infrared Spectra: Quantitative Similarity Measures and Force Fields WOS:000535226900034 published article about HARMONIC VIBRATIONAL FREQUENCIES; SCALE FACTORS; ORGANIC LIQUIDS; SPECTROSCOPY; DENSITY; ENERGY; IR; FUNCTIONALS; COEFFICIENT; MOLECULES in [Henschel, Henning; Andersson, Alfred T.; Jespers, Willem; Ghahremanpour, Mohammad Mehdi; van der Spoel, David] Uppsala Univ, Uppsala Ctr Computat Chem, Dept Cell & Mol Biol, Sci Life Lab, SE-75124 Uppsala, Sweden; [Ghahremanpour, Mohammad Mehdi] Yale Univ, Dept Chem, 225 Prospect St, New Haven, CT 06520 USA in 2020, Cited 53. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Category: ethers-buliding-blocks

Infrared spectroscopy can provide significant insight into the structures and dynamics of molecules of all sizes. The information that is contained in the spectrum is, however, often not easily extracted without the aid of theoretical calculations or simulations. We present here the calculation of the infrared spectra of a database of 703 gas phase compounds with four different force fields (CGenFF, GAFF-BCC, GAFF-ESP, and OPLS) using normal-mode analysis. Modern force fields increasingly use virtual sites to describe, e.g., lone-pair electrons or the o -holes on halogen atoms. This requires some adaptation of code to perform normal-mode analysis of such compounds, the implementation of which into the GROMACS software is briefly described as well. For the quantitative comparison of the obtained spectra with experimental reference data, we discuss the application of two different statistical correlation coefficients, Pearson and Spearman. The advantages and drawbacks of the different methods of comparison are discussed, and we find that both methods of comparison give the same overall picture, showing that present force field methods cannot match the performance of quantum chemical methods for the calculation of infrared spectra.

Category: ethers-buliding-blocks. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Wetchemical synthesis of FePt nanoparticles: Tuning of magnetic properties and biofunctionalization for hyperthermia therapy WOS:000458152000015 published article about DESIGN; GOLD; SIZE in [Goswami, Madhuri Mandal] SN Bose Natl Ctr Basic Sci, Sect 3,Block JD, Kolkata 700106, India; [Das, Arpita; De, Debarati] Univ Calcutta, CRNN, Sect 3,Block JD, Kolkata 700106, India in 2019.0, Cited 33.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Quality Control of Diphenyl oxide

This work reports a new approach of synthesis of FePt nanoparticles in aqueous medium using cetyl trimethylammonium bromide (CTAB) surfactant as a capping agent and the influence of change of its concentration on the size of the particles. Tuning of magnetic properties has also been done by changing the CTAB concentrations. Here at higher CTAB concentration, particles formed are of smaller size compared to the size prepared in lower micellar concentration. The ordering parameter of the particles after annealing at 550 degrees C with the variation of particle size is also studied. The magnetic properties of these particles are studied and the effect of particle phase and size on magnetic property is also investigated. The particles are prepared in aqueous medium because water soluble particles are useful for hyperthermia therapy. Heating abilities of the particles under AC magnetic field are also checked with change in their size. The studies on interaction of particles with cancer cell line was also performed with probing the cell by fluorescence imaging technique after bio-functionalization of the particles by sodium oleate and fluorescent dye rhodamine-B-isothiocyanate (RITC). All these preliminary studies indicate a promising applicability of the particles for localized cancer treatment by magnetic field induced hyperthermia therapy.

Quality Control of Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Goswami, MM; Das, A; De, D or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Application In Synthesis of Benzyl ether. Cotin, G; Perton, F; Petit, C; Sall, S; Kiefer, C; Begin, V; Pichon, B; Lefevre, C; Mertz, D; Greneche, JM; Begin-Colin, S in [Cotin, Geoffrey; Perton, Francis; Kiefer, Celine; Begin, Valentin; Pichon, Benoit; Lefevre, Christophe; Mertz, Damien; Begin-Colin, Sylvie] Univ Strasbourg, CNRS, Inst Phys & Chim Mat Strasbourg, UMR 7504, F-67034 Strasbourg, France; [Cotin, Geoffrey; Perton, Francis; Kiefer, Celine; Begin, Valentin; Pichon, Benoit; Lefevre, Christophe; Mertz, Damien; Begin-Colin, Sylvie] Univ Strasbourg, Fdn IcFRC, Labex CSC, F-67083 Strasbourg, France; [Petit, Corinne; Sall, Secou] Inst Chim & Proc Energie Environm & Sante ICPEES, F-67087 Strasbourg, France; [Greneche, Jean-Marc] Univ Maine, Inst Mol & Mat Mans IMMM UMR CNRS 6283, F-72085 Le Mans 9, France published Harnessing Composition of Iron Oxide Nanoparticle: Impact of Solvent-Mediated Ligand-Ligand Interaction and Competition between Oxidation and Growth Kinetics in 2020, Cited 86. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

The composition of metal oxide nanoparticles is of great importance for their applications because defects and/or deviation from stoichiometry strongly affect their physical properties. We report here on the crucial role of synthesis parameters such as solvent, ligand, and iron precursors on the composition of spinel iron oxide nanoparticles synthesized by the thermal decomposition method. At first, the investigation of the thermal decomposition of iron stearates bearing either two or three stearate chains by thermogravimetric analysis, infrared spectroscopy, and Mossbauer spectrometry as a function of temperature and syntheses with only oleic acid and iron stearate confirmed that the composition of the first nuclei is wustite Fe1-xO. The synthesis of nanoparticles with high sizes requires the use of very high boiling point solvents to ensure an effective growth step. We observed that when the grain growth and oxidation kinetics are similar, nanoparticles with a spinel composition and no defects are produced. An oxidation rate slower than the nuclei growth rate favors the formation of core-shell Fe1-xO@Fe3-xO4 NPs. The oxidation kinetics is shown to be influenced by surfactant and solvent natures. Indeed, surfactants such as oleic acid form a dense monolayer at the nuclei surface, and oxidation kinetics will depend on this monolayer permeability. Temperature, solvents with high surfactant affinity, deprotonated surfactants, or decomposition products of solvents affect the monolayer stability and thus the nanoparticle composition. The solvents’ nature and solvent-mediated ligand-ligand interactions are thus evidenced to be important parameters to control the formation of defect-free and stoichiometric oxide nanoparticles.

Application In Synthesis of Benzyl ether. Bye, fridends, I hope you can learn more about C14H14O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Authors Re, E; Le Goff, X; Toquer, G; Maynadie, J; Meyer, D in ROYAL SOC CHEMISTRY published article about OXIDE NANOCRYSTALS SYNTHESIS; MECHANICAL-PROPERTIES; HOT-INJECTION; NANOPARTICLES; NANOSTRUCTURES; ASSEMBLIES; MONOLAYERS; ROUTE in [Re, Elisa; Le Goff, Xavier; Toquer, Guillaume; Maynadie, Jerome; Meyer, Daniel] Univ Montpellier, CEA, ENSCM, CNRS,ICSM, Marcoule, France in 2020, Cited 61. Name: Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Obtaining bulk materials ordered at the nanoscale using nanoparticles as building blocks is a new challenge for scientists and is of primary interest in some research areas. In this study, we developed a simple one-pot route towards nanostructured hybrid materials based on uranium oxide through a non-hydrolytic condensation process under mild solvothermal conditions (T = 160 degrees C) using ditopic organic linkers as structuring agents. The obtained materials present a sand rose morphology composed of agglomerated nanometric sheets with a lamellar substructure. Nanometric sheets are composed of inorganic fringes consisting of a studtite phase [(UO2)O-2(H2O)(2)]center dot 2H(2)O that alternates with organic fringes formed by the structuring organic linker. A multiparametric study based on SAXS experiments and TEM analyses has highlighted the control of structural parameters by varying some synthesis conditions. The interlamellar distances are tunable from 1.60 nm to 1.94 nm through the length of the structuring linker and the inter-sheet distance from 1.85 nm to 2.10 nm through synthesis temperature. This efficient one-pot route appears to be very promising for the production of tunable multiscale nanostructured hybrid materials and can be implemented in many research areas, paving the way for various applications.

Name: Benzyl ether. Welcome to talk about 103-50-4, If you have any questions, you can contact Re, E; Le Goff, X; Toquer, G; Maynadie, J; Meyer, D or send Email.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

HPLC of Formula: C14H14O. Authors Aniceto, JPS; Zezere, B; Silva, CM in ELSEVIER published article about in [Aniceto, Jose P. S.; Zezere, Bruno; Silva, Carlos M.] Univ Aveiro, CICECO, Dept Chem, P-3810193 Aveiro, Portugal in 2021, Cited 39. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

The molecular diffusion coefficient is fundamental to estimate dispersion coefficients, convective mass transfer coefficients, etc. Since experimental diffusion data is scarce, there is significant demand for accurate models capable of providing reliable diffusion coefficient estimations. In this work we applied machine learning algorithms to develop predictive models to estimate diffusivities of solutes in supercritical carbon dioxide. A database of experimental data containing 13 properties for 174 binary systems totaling 4917 data points was used in the training of the models. Five machine learning algorithms were evaluated and the results were compared with three commonly used classic models. The best results were found using the Gradient Boosted algorithm which showed an average absolute relative deviation (AARD) of 2.58 % (pure prediction). This model has five parameters: temperature, density, solute molar mass, solute critical pressure and solute acentric factor. For the same dataset, the classic Wilke-Chang equation showed AARD of 12.41 %. The developed model is provided as command line program. (C) 2021 Elsevier B.V. All rights reserved.

HPLC of Formula: C14H14O. Welcome to talk about 103-50-4, If you have any questions, you can contact Aniceto, JPS; Zezere, B; Silva, CM or send Email.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recommanded Product: Diphenyl oxide. I found the field of Environmental Sciences & Ecology very interesting. Saw the article Spatiotemporal distribution, source apportionment and ecological risk assessment of PBDEs and PAHs in the Guanlan River from rapidly urbanizing areas of Shenzhen, China published in 2019.0, Reprint Addresses Xu, N (corresponding author), Peking Univ, Shenzhen Grad Sch, Sch Environm & Energy, Key Lab Heavy Met Pollut Control & Reutilizat, Shenzhen 518055, Peoples R China.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide.

In this study, nine congeners of polybrominated diphenyl ethers (PBDEs) and sixteen congeners of polycyclic aromatic hydrocarbons (PAHs) were measured in water samples to elucidate their spatial distribution, congener profiles, sources and ecological risks in the Guanlan River during both the dry season (DS) and the wet season (WS). The concentration of Sigma 9PBDE ranged from 58.40 to 186.35 ng/L with an average of 115.72 ng/L in the DS, and from 8.20 to 37.80 ng/L with an average of 22.15 ng/L in the WS. Meanwhile, the concentration of Sigma(16)PAHs was ranged from 121.80 to 8371.70 ng/L with an average of 3271.18 ng/L in the DS and from 1.85 to 7124.25 ng/L with an average of 908.11 ng/L in the WS. The concentrations of PBDEs and PAHs in the DS were significantly higher than those in the WS, probably due to the dilution of the river during the rainy season. Moreover, the spatial distribution of pollutants revealed decreasing trend in the concentration from upstream to downstream and almost identical pattern was observed during both seasons. The source apportionment suggested that penta-BDE and to some extent octa-BDE commercial products were major sources of PBDEs in the study area. However, the sources of PAHs were mainly comprised of fossil fuels and biomass burning, followed by the petroleum products and their mixtures. The results of the ecological risk assessment indicated PBDEs contamination posed high ecological risks, while PAHs exhibited low or no ecological risks in the study area. Consistent with the environmental levels, the ecological risks of pollutants were relatively lower in the WS, compared to that in the DS. The results from this study would provide valuable baseline data and technical support for policy makers to protect the ecological environment of the Guanlan River. (C) 2019 Elsevier Ltd. All rights reserved.

Welcome to talk about 101-84-8, If you have any questions, you can contact Liang, XX; Junaid, M; Wang, ZF; Li, TH; Xu, N or send Email.. Recommanded Product: Diphenyl oxide

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Solvent effect in the nonaqueous synthesis of ZrO2 nanoparticles under alkaline conditions WOS:000501075200011 published article about SOLVOTHERMAL SYNTHESIS; SIZE DEPENDENCE; ZIRCONIA; TEMPERATURE; STABILIZATION; NANOCRYSTALS in [Gambe, Jess; Jouin, Jenny; Remondiere, Fabien; Thomas, Philippe; Masson, Olivier] Ctr Europeen Ceram, IRCER UMR 7315, 12 Rue Atlantis, F-87068 Limoges, France in 2020, Cited 37. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Name: Benzyl ether

This work deals with the synthesis of zirconium dioxide (ZrO2) nanoparticles (NPs) in different solvents and their structural characterization for better understanding the oxygen donor solvent/zirconium precursor/NPs structure relationships. By selecting solvents over their capacity to produce different crystalline states from alkalinized zirconium alkoxide, spherical nanoparticles with a size of about 1.3-3 nm and a narrow size distribution were elaborated using a nonaqueous solvothermal sol-gel route. Conventional X-ray diffraction (XRD) was used to determine the average structure and crystallite size of the nanoparticles. Well-crystallized and single-phased nanoparticles with average monoclinic and tetragonal structure were obtained with benzaldehyde and benzyl alcohol, respectively, and a much distorted structure was observed for the synthesis in anisole. The atomic pair distribution functions (PDF) of the samples were also analyzed to access the local structure of the nanoparticles. The PDF of the benzaldehyde-prepared sample is consistent with the monoclinic structure. However, the local structure of nanoparticles synthesized with benzyl alcohol does not fully conform to the tetragonal structure observed by XRD, but exhibits monoclinic-like distortions. Lastly, the anisole-prepared nanoparticles present large structural distortions at the medium range and monoclinic local structural features. The restructuring of this last sample was studied by post-treatments in different solvents and leads to the expression of the tetragonal polymorph. Moreover, it seems that the main structural features are obtained in the early stages of the nanoparticles’ formation.

Name: Benzyl ether. About Benzyl ether, If you have any questions, you can contact Gambe, J; Jouin, J; Remondiere, F; Thomas, P; Masson, O or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Category: ethers-buliding-blocks. In 2020 ENERG FUEL published article about ZSM-5 ZEOLITE; Y ZEOLITE; LIGNITE; HYDROGENATION; GUAIACOL; HYDRODEOXYGENATION; HYDROGENOLYSIS; ACCESSIBILITY; SITES; NI in [Kang, Yu-Hong; Wei, Xian-Yong; Liu, Guang-Hui; Ma, Xiang-Rong; Gao, Yong; Li, Xiao; Li, Yan Jun; Zong, Zhi-Min] China Univ Min & Technol, Minist Educ, Key Lab Coal Proc & Efficient Utilizat, Xuzhou 221116, Jiangsu, Peoples R China; [Kang, Yu-Hong; Wei, Xian-Yong; Ma, Xiang-Rong; Gao, Yong; Li, Xiao; Li, Yan Jun; Ma, Ya-Jun; Yan, Long] Yulin Univ, Shaanxi Key Lab Low Metamorph Coal Clean Utilizat, Sch Chem & Chem Engn, Yulin 71900, Shaanxi, Peoples R China in 2020, Cited 29. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

A novel and highly active zeolite Y/ZSM-5 composite zeolite (CZ)-supported nickel catalyst (Ni/CZ with 10% of Ni loading) was prepared by modified deposition-precipitation to uniformly disperse Ni nanoparticles (NNPs) onto CZ. Hecaogou subbituminous coal was exhaustively extracted with isometric carbon disulfide/acetone mixed solvent to afford the extractable portion and inextractable portion (IEP). Ethanol-soluble portion (ESP) was obtained by ethanolyzing the IEP at 300 degrees C and subjected to catalytic hydroconversion (CHC) over Ni-10%/CZ at 160 degrees C to afford catalytically hydroconverted ESP (CHCESP). Both ESP and CHCESP were analyzed with a Fourier transform infrared spectrometer, gas chromatograph/mass spectrometer (GC/MS), and quadrupole exactive orbitrap mass spectrometer. The results show that the relative contents (RCs) of both chain alkanes and hydroarenes in CHCESP are significantly higher than those in ESP and cyclanes and alkenes were only detected in CHCESP, while the RCs of both arenes and oxygen-containing organic compounds in CHCESP are much lower than those in ESP and nitrogen- and/or sulfur-containing organic compounds were only detected in ESP with GC/MS. According to the CHC of oxybis(methylene)dibenzene (OBMDB), Ni-10%/CZ can effectively activate H-2 to biatomic active hydrogen (H center dot center dot center dot H) and the resulting H center dot center dot center dot H was heterolytically split into an immobile H- attached on Ni/CZ and a mobile H+. H+ transfers to an oxygen atom (OA) in OBMDB and cleaves the C-O bridged bond to produce phenylmethanol (PM) and benzylium, followed by H- abstraction from the Ni/CZ surface by benzylium to form toluene. H+ transfer to the OA in PM also leads to the cleavage of the C-O bond in PM to produce H2O and benzylium, which abstracts H- from the Ni/CZ surface to yield toluene. H center dot center dot center dot H transfer to the benzene ring in toluene generates methylcyclohexane. Therefore, Ni-10%/CZ catalyzes both H+ and H center dot center dot center dot H transfer. In addition, it proved to be stable for the CHC of OBMDB after 3 cycles.

Category: ethers-buliding-blocks. Bye, fridends, I hope you can learn more about C14H14O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem