Month: December 2021

Computed Properties of C12H10O. Authors Wang, SW; He, ZH; Chen, JG; Wang, K; Wang, ZY; Guo, PP; Lan, J; Wang, WT; Liu, ZT in ROYAL SOC CHEMISTRY published article about in [Wang, Sen-Wang; Chen, Jian-Gang; Liu, Zhao-Tie] Shaanxi Normal Univ, Sch Chem & Chem Engn, Xian 710119, Peoples R China; [He, Zhen-Hong; Wang, Kuan; Wang, Zhong-Yu; Guo, Pan-Pan; Lan, Jie; Wang, Weitao; Liu, Zhao-Tie] Shaanxi Univ Sci & Technol, Shaanxi Key Lab Chem Addit Ind, Coll Chem & Chem Engn, Xian 710021, Peoples R China in 2021.0, Cited 65.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Hydrogenolysis of biomass-derived lignin sources is highly important for the conversion of renewable biomass resources to biofuels. However, lots of developed catalysts suffer from the drawbacks of expensive precious metal catalysts and/or operation under harsh conditions. In the present work, Co-Ni bimetallic catalysts were prepared and applied in catalyzing hydrogenolysis of C-aryl-O aromatic ethers with high activities under the promotion of Nb2C MXene additive. Especially, the hydrogenolysis of diphenyl ether (DPE), a 4-O-5 model compound, to cyclohexane (cy) and cyclohexyl alcohol (cy-ol) could be achieved over the Co2Ni1Ox-Nb2C MXene catalytic system at 120 degrees C and under 5 bar of H-2, which are mild conditions in comparison with those for the developed heterogeneous precious-metal-free catalysts. The excellent catalytic performances stemmed from the strong interaction between Co and Ni species and the promotion of Lewis acidic sites offered by Nb2C MXene. The proposed reaction pathway involved the direct hydrogenolysis of DPE route, in which DPE was initially hydrogenolyzed to benzene and phenol. They were further hydrogenated to cy and cy-ol. The present work not only develops a noble-metal-free bimetallic catalyst for utilization of biomass-derived lignin sources, but also provides a novel strategy for using the Nb2C MXene material.

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Ether – Wikipedia,
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An article Surface elemental distribution effect of Pt-Pb hexagonal nanoplates for electrocatalytic methanol oxidation reaction WOS:000531430100009 published article about HIGH-INDEX FACETS; OXYGEN REDUCTION; CONCAVE NANOCUBES; FUEL-CELLS; NANOPARTICLES; MECHANISM; ELECTROOXIDATION; NUCLEATION; GROWTH; CO in [Kim, Hee Jin; Ahn, Yong-Deok; Kim, Jeonghyeon; Choi, Sang-Il] Kyungpook Natl Univ, Dept Chem, Daegu 41566, South Korea; [Kim, Hee Jin; Ahn, Yong-Deok; Kim, Jeonghyeon; Choi, Sang-Il] Kyungpook Natl Univ, Green Nano Mat Res Ctr, Daegu 41566, South Korea; [Kim, Kyoung-Su; Hong, Jong Wook] Univ Ulsan, Dept Chem, Ulsan 44610, South Korea; [Jeong, Yeon Uk] Kyungpook Natl Univ, Sch Mat Sci & Engn, Daegu 41566, South Korea in 2020, Cited 40. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Recommanded Product: Benzyl ether

Bimetallic Pt-based catalysts have been extensively investigated to enhance the performance of direct methanol fuel cells (DMFCs) because CO, a by-product, reduces the activity of the pure Pt catalysts. Herein, we synthesized Pt-Pb hexagonal nanoplates as a model catalyst for the methanol oxidation reaction (MOR) and further controlled the Pt and Pb distributions on the surface of the nanoplates through acetic acid (HAc) treatment. As a result, we obtained Pt-Pb nanoplates and HAc-treated Pt-Pb nanoplates with homogeneous and heterogeneous distributions of the Pt-Pb alloy surfaces, respectively. We showed that the MOR activity and stability of the Pt-Pb nanoplates improved compared to those of the HAc-treated Pt-Pb nanoplates, mainly due to the enhanced CO tolerance and the modified electronic structure of Pt under the influence of the oxophilic Pb. (C) 2020, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

Recommanded Product: Benzyl ether. About Benzyl ether, If you have any questions, you can contact Kim, HJ; Ahn, YD; Kim, J; Kim, KS; Jeong, YU; Hong, JW; Choi, SI or concate me.

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Recommanded Product: 101-84-8. In 2020 POLYHEDRON published article about N-HETEROCYCLIC CARBENE; COX-2 SELECTIVE INHIBITORS; COUPLING REACTIONS; NANO-PARTICLES; DIARYL ETHERS; ARYL HALIDES; REDUCTIVE ELIMINATION; DIRECT C5-ARYLATION; EFFICIENT CATALYST; IMIDAZOLES in [Bhatt, Ramprasad] Birla Inst Technol & Sci, Dept Chem, Pilani Campus, Pilani 333031, Rajasthan, India; [Sharma, Alpesh K.] Indian Inst Technol Delhi, Dept Chem, New Delhi 110016, India; [Himanshi; Joshi, Hemant] Cent Univ Rajasthan, Sch Chem Sci & Pharm, Dept Chem, ISC Lab, NH 8, Ajmer 305817, Rajasthan, India; [Bhuvanesh, Nattamai] Texas A&M Univ, Dept Chem, POB 30012, College Stn, TX 77842 USA in 2020, Cited 73. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

This report describes the syntheses of N,E (E = S, Se) coordinated bidentate palladium complexes, by the reaction of N-(2-bromobenzyl)-2-(phenylthio/selanyl)ethanamine (3, 4) with [PdCl2(CH3CN)(2)]. The new ligands and palladium complexes were characterized by techniques like H-1, C-13{H-1} NMR, IR, and elemental analysis. The coordination modes of ligand with palladium precursor in complexes 5 and 6 were authenticated by single crystal X-ray diffraction. The complexes possess distorted square planar geometry around palladium center. Thermally robust and air stable complexes 5 and 6 were used as catalyst for regioselective arylation of imidazole and O-arylation of phenol. In case of regioselective arylation of imidazole, the reaction proceeds smoothly under mild reaction conditions, only 2.0 mol% of catalyst loading is required to achieve high yield (76-92%). This protocol is applicable to a broad substrate scope showing excellent tolerance towards different functional groups. Whereas for O-arylation of phenol also only 2.0 mol% catalyst loading is sufficient to give good yield (71-92%) with excellent tolerance towards a broad range of functional groups. Among sulfur and selenium coordinated ligands, selenium ligand coordinated complex, was found to outperform the catalytic reactions in both cases as compare to sulfur ligand. The mercury and triphenylphosphine poisoning tests suggest homogeneous nature of catalysis. (C) 2020 Elsevier Ltd. All rights reserved.

Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.. Recommanded Product: 101-84-8

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Ether – Wikipedia,
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An article A comparative study of nitrobenzene reduction using model catalysts WOS:000456147000005 published article about OXIDATIVE DEHYDROGENATION; CARBON NANOTUBES; LIQUID-PHASE; EFFICIENT; GRAPHENE; HYDROGENATION; CARBOCATALYST; NITROARENES; OXIDE; BN in [Wu, Shuchang] Taizhou Univ, Sch Pharmaceut & Mat Engn, Taizhou 318000, Zhejiang, Peoples R China; [Lin, Yangming; Wen, Guodong; Liu, Hongyang; Su, Dang Sheng] Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China; [Zhong, Bingwei] Zhejiang A&F Univ, JiYang Coll, 77 Puyang Rd, Zhuji 311800, Peoples R China in 2019, Cited 28. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. HPLC of Formula: C14H14O

A zigzag-type quinone performs better than an armchair-type quinone in the reduction of nitrobenzene. When different kinds of functionalities co-exist, the reaction is dominated by the most active sites, but the most negative sites should also be taken into consideration if the acitive sites have zigzag structures.

HPLC of Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Wu, SC; Lin, YM; Zhong, BW; Wen, GD; Liu, HY; Su, DS or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recommanded Product: Diphenyl oxide. Zhenova, A; Pellis, A; Milescu, RA; McElroy, CR; White, RJ; Clark, JH in [Zhenova, Anna; Pellis, Alessandro; Milescu, Roxana A.; McElroy, Con Robert; Clark, James H.] Univ York, Dept Chem, Green Chem Ctr Excellence, York YO10 5DD, N Yorkshire, England; [White, Robin J.] Fraunhofer Inst Solar Energy Syst ISE, Heidenhofstr 2, D-79110 Freiburg, Germany; [White, Robin J.] Netherlands Org Appl Sci Res TNO, Locatie Eindhoven, High Tech Campus 25, NL-5656 AE Eindhoven, Netherlands published Solvent Applications of Short-Chain Oxymethylene Dimethyl Ether Oligomers in 2019.0, Cited 43.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Short-chain oxymethylene dimethyl ethers (OMEs) (molecular formula: H3CO-(CH2O)(n)-CH3, where n = 3-5) have previously been studied as diesel-like fuels and fuel additives. OMEs can be produced from sustainably sourced methanol, and tests indicate that they are neither genotoxic nor mutagenic. In this report, their potential as solvents has been investigated to expand the bio-derived solvent space. According to traditional solvatochromic parameters, a commercial mixture of OME3-5 and its individual components (OME3, OME4, and OME5) have solvation properties similar to problematic industrial ether solvents such as 1,4-dioxane. Peroxide formation, one of the chief dangers of classical ether solvents, was found to occur much more slowly in OMEs than in conventional solvents such as tetrahydrofuran (THE), demonstrating an improved safety profile. The commercial OME3-5 mixture was found to be broadly miscible with organic solvents but immiscible with water, suggesting potential application in aqueous extractions. It performed well in the dissolution of polystyrene and removal of paints and coatings, indicating OME3-5 may suitable to replace dichloromethane in polymer recycling, polymer welding, and cleaning applications. To further demonstrate applicability as a solvent, this mixture was shown to facilitate a model Suzuki coupling reaction at rates similar to cyclopentyl methyl ether, which is currently marketed as a green ether. Finally, OME3-5 proved a suitable solvent for enzymatic polymerization, giving high yields, moderately high degrees of polymerization, and remarkably narrow dispersity values.

Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.. Recommanded Product: Diphenyl oxide

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Product Details of 103-50-4. Cheng, BB; Wang, W; Niu, XG; Ren, YC; Liu, T; Cao, H; Wang, SH; Tu, YF; Chen, JX; Liu, SW; Yang, XC; Chen, JJ in [Cheng, Binbin; Wang, Wei; Niu, Xiaoge; Ren, Yichang; Liu, Ting; Cao, Hao; Wang, Shuanghu; Tu, Yingfeng; Chen, Jingxuan; Liu, Shuwen; Yang, Xuchao; Chen, Jianjun] Southern Med Univ, Sch Pharmaceut Sci, Guangdong Prov Key Lab New Drug Screening, Guangzhou 510515, Peoples R China published Discovery of Novel and Highly Potent Resorcinol Dibenzyl Ether-Based PD-1/PD-L1 Inhibitors with Improved Drug-like and Pharmacokinetic Properties for Cancer Treatment in 2020, Cited 19. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

A series of programmed cell death-1 (PD-1)/programmed cell death ligand 1 (PD-L1) inhibitors based on the resorcinol diphenyl ether scaffold were discovered by incorporating hydrophilic moieties into the side chain and converting into the corresponding hydrochloride salt. Among these compounds, P18 showed the highest inhibitory activity against PD-1/PD-L1 with an IC50 value of 9.1 nM in a homogeneous time-resolved fluorescence binding assay. Besides, P18 promoted HepG2 cell death dose dependently in a HepG2/PD-L1 and Jurkat/PD-1 coculture cell model. Further, P18 demonstrated significantly higher water solubility (17.61 mg/mL) and improved pharmacokinetics (e.g., t(1/2) of similar to 20 h and oral bioavailability of 12%) than the previous analogues. Moreover, P18 was highly effective in suppressing tumor growth in an immune checkpoint humanized mouse model without apparent toxicity. Collectively, these results suggest that compound P18 represents a promising PD-1/PD-L1 inhibitor worthy of further investigation as a potential anticancer agent.

Welcome to talk about 103-50-4, If you have any questions, you can contact Cheng, BB; Wang, W; Niu, XG; Ren, YC; Liu, T; Cao, H; Wang, SH; Tu, YF; Chen, JX; Liu, SW; Yang, XC; Chen, JJ or send Email.. Product Details of 103-50-4

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Authors Klein, T; Kickelbick, G in IOP PUBLISHING LTD published article about POLYMORPHIC PHASE-TRANSFORMATIONS; AL NANOPARTICLES; ELECTRICAL EXPLOSION; OLEIC-ACID; SIZE; NICKEL; PASSIVATION; NANOPOWDERS; GENERATION; COMBUSTION in [Klein, Thomas; Kickelbick, Guido] Saarland Univ, Inorgan Solid State Chem, Campus C4-1, D-66123 Saarbrucken, Germany in 2020.0, Cited 65.0. SDS of cas: 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Submicron Al particles can be used in energy materials, as reducing agents, or for the formation of aluminides. Their standard electrode potential and their reactivity towards oxygen makes their synthesis a challenging task. Here we present a thermal decomposition approach starting from triisobutylaluminium (TIBAL) as a precursor. This compound can be decomposed in refluxing diphenylether as a high-boiling solvent and in the presence of metallic nanoparticles of Ni, Ru or Ag acting as seeds. The resulting particles revealed sizes of around 100 nm. Passivation of the Al particles is possible in an optional second step after the synthesis by adding oleic acid resulting in the formation of organically capped Al particles. The suitability of these submicron particles for the synthesis of aluminides was studied by reacting the synthesized particles with Ru powders, resulting in the formation of the respective aluminide.

SDS of cas: 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Klein, T; Kickelbick, G or concate me.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Machine learning prediction of coordination energies for alkali group elements in battery electrolyte solvents WOS:000502767400009 published article about LITHIUM-ION TRANSFER; NONCOVALENT INTERACTIONS; THEORETICAL-ANALYSIS; DENSITY FUNCTIONALS; SODIUM; THERMOCHEMISTRY; IDENTIFICATION; INTERFACE; DISCOVERY; KINETICS in [Ishikawa, Atsushi; Sodeyama, Keitaro; Igarashi, Yasuhiko] Japan Sci & Technol Agcy JST, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 3330012, Japan; [Ishikawa, Atsushi; Tateyama, Yoshitaka] Natl Inst Mat Sci, Ctr Green Res Energy & Environm Mat GREEN, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan; [Ishikawa, Atsushi; Tateyama, Yoshitaka] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan; [Ishikawa, Atsushi; Sodeyama, Keitaro; Tateyama, Yoshitaka] Natl Inst Mat Sci, Ctr Mat Res Informat Integrat cMI2, Res & Serv Div Mat Data & Integrated Syst MaDIS, 1-2-1 Sengen, Tsukuba, Ibaraki 3050047, Japan; [Ishikawa, Atsushi; Sodeyama, Keitaro] Kyoto Univ, Elements Strategy Initiat Catalysts & Batteries, Nishikyo Ku, 1-30 Goiyo Oham, Kyoto 6158245, Japan; [Igarashi, Yasuhiko; Nakayama, Tomofumi; Tateyama, Yoshitaka; Okada, Masato] Univ Tokyo, Grad Sch Frontier Sci, 5-1-5 Kashiwanoha, Kashiwa, Chiba 2778561, Japan in 2019.0, Cited 31.0. Formula: C12H10O. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

We combined a data science-driven method with quantum chemistry calculations, and applied it to the battery electrolyte problem. We performed quantum chemistry calculations on the coordination energy (E-coord) of five alkali metal ions (Li, Na, K, Rb, and Cs) to electrolyte solvent, which is intimately related to ion transfer at the electrolyte/electrode interface. Three regression methods, namely, multiple linear regression (MLR), least absolute shrinkage and selection operator (LASSO), and exhaustive search with linear regression (ES-LiR), were employed to find the relationship between E-coord and descriptors. Descriptors include both ion and solvent properties, such as the radius of metal ions or the atomic charge of solvent molecules. Our results clearly indicate that the ionic radius and atomic charge of the oxygen atom that is connected to the metal ion are the most important descriptors. Good prediction accuracy for E-coord of 0.127 eV was obtained using ES-LiR, meaning that we can predict E-coord for any alkali ion without performing quantum chemistry calculations for ion-solvent pairs. Further improvement in the prediction accuracy was made by applying the exhaustive search with Gaussian process, which yields 0.016 eV for the prediction accuracy of E-coord.

Formula: C12H10O. Welcome to talk about 101-84-8, If you have any questions, you can contact Ishikawa, A; Sodeyama, K; Igarashi, Y; Nakayama, T; Tateyama, Y; Okada, M or send Email.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Efficient Catalysts In situ Generated from Zinc, Amide and Benzyl Bromide for Epoxide/CO2 Coupling Reaction at Atmospheric Pressure WOS:000458691300019 published article about CARBON-DIOXIDE; CYCLIC CARBONATES; CHEMICAL FIXATION; HIGHLY EFFICIENT; IONIC LIQUIDS; CO2 REDUCTION; CYCLOADDITION; MILD; COMPLEXES; SYSTEM in [Zhang, Shuai; He, Liang-Nian] Nankai Univ, Coll Chem, State Key Lab, Tianjin 300071, Peoples R China; [Zhang, Shuai; He, Liang-Nian] Nankai Univ, Coll Chem, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China; [Zhang, Shuai; Han, Feng; Yan, Shaorui; He, Mingyue; Miao, Chengxia] Inst Shandong Agr Univ, Coll Chem & Mat Sci, Tai An 271018, Shandong, Peoples R China in 2019, Cited 58. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Application In Synthesis of Benzyl ether

Herein, in situ generated efficient catalysts were designed for fixation of CO2 to cyclic carbonates under mild conditions. Zinc bromide and N,N-dibenzyl-N,N-dimethylammonium bromide, being proved as active catalyst species, were in situ generated from cheap Zn powder, dimethyl formamide and benzyl bromide, and catalyzed the cycloaddition reaction of CO2 and various terminal epoxides in moderate to excellent yields at 80 degrees C and atmospheric pressure of CO2. The protocol circumvents the preparation of active catalysts, simultaneously possesses good catalytic activity under mild conditions.

Welcome to talk about 103-50-4, If you have any questions, you can contact Zhang, S; Han, F; Yan, SR; He, MY; Miao, CX; He, LN or send Email.. Application In Synthesis of Benzyl ether

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Category: ethers-buliding-blocks. In 2019 APPL CATAL A-GEN published article about ACID IONIC LIQUIDS; EFFICIENT SYNTHESIS; CHEMICAL-EQUILIBRIUM; METHANOL; REDUCTION; SITES; OME; PARAFORMALDEHYDE; IMPROVEMENT; TRIOXANE in [Wang, Ruiyi; Wu, Zhiwei; Li, Zhikai; Qin, Zhangfeng; Chen, Chengmeng; Zheng, Zhanfeng; Wang, Guofu; Fan, Weibin; Wang, Jianguo] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, POB 165, Taiyuan 030001, Shanxi, Peoples R China; [Chen, Chengmeng] Chinese Acad Sci, Inst Coal Chem, Key Lab Carbon Mat, Taiyuan 030001, Shanxi, Peoples R China in 2019, Cited 48. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Polyoxymethylene dimethyl ethers (PODE, with the formula of CH3O-(CH2O)(n)-CH3), as a promising environmentally benign diesel fuel or additive with an enormous potential in the reduction of soot and NIC, emissions, can be efficiently synthesized from methanol derivatives such as dimethoxymethane (DMM) and trioxymethylene (TOM), which requests a proper catalyst of high performance. In this work, the catalytic performance of graphene oxide (GO) in the synthesis of PODEn as well as its relation to the catalyst structure was thoroughly investigated. The results indicate that GO is an excellent catalyst in the synthesis of PODEn from DMM and TOM; a TOM conversion of 94.6% and selectivity of 86.0% to PODE2-8 are achieved under mild reaction conditions, which is superior to the majority of the state-of-the-art catalysts. Meanwhile, the active species and characteristic layer structure of GO sheets catalytically responsible for PODEn formation were discriminated through selectively removing certain surface functional groups, thermally annealing at different temperatures, and carefully comparing with a series of model compounds. The results illustrate that the superior catalytic performance of GO in the PODEn synthesis should be ascribed to a synergy between the surface sulfonyl, hydroxyl and carboxyl groups present on the GO surface and the unique layered structure of GO sheets, wherein the surface sulfonyl groups act as the main active sites. The insights shown in this work are beneficial to a deep understanding on the catalytic principle of GO and development of efficient catalyst for the synthesis of PODEn.

Welcome to talk about 101-84-8, If you have any questions, you can contact Wang, RY; Wu, ZW; Li, ZK; Qin, ZF; Chen, CM; Zheng, ZF; Wang, GF; Fan, WB; Wang, JG or send Email.. Category: ethers-buliding-blocks

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem