An article Breaking C-O Bonds with Uranium: Uranyl Complexes as Selective Catalysts in the Hydrosilylation of Aldehydes WOS:000489204000019 published article about RING-OPENING POLYMERIZATION; METAL-FREE; CRYSTAL-STRUCTURE; REDUCTIVE DEPOLYMERIZATION; CARBONYL-COMPOUNDS; ALDOL CONDENSATION; SYMMETRIC ETHERS; CARBOXYLIC-ACIDS; CYCLOTRIMERIZATION; ETHERIFICATION in [Monsigny, Louis; Thuery, Pierre; Berthet, Jean-Claude; Cantat, Thibault] Univ Paris Saclay, CEA Saclay, CNRS, NIMBE,CEA, F-91191 Gif Sur Yvette, France in 2019, Cited 76. Computed Properties of C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4
We report herein the possibility to perform the hydrosilylation of carbonyls using actinide complexes as catalysts. While complexes of the uranyl ion [UO2](2+) have been poorly considered in catalysis, we show the potentialities of the Lewis acid [UO2(OTf)(2)] (1) in the catalytic hydrosilylation of a series of aldehydes. [UO2(OTf)(2)] proved to be a very active catalyst affording distinct reduction products depending on the nature of the reductant. With Et3SiH, a number of aliphatic and aromatic aldehydes are reduced into symmetric ethers, while (Pr3SiH)-Pr-i yielded silylated alcohols. Studies of the reaction mechanism led to the isolation of aldehyde/uranyl complexes, [UO2(OTf)(2)(4-Me2N-PhCHO)(3)], [UO2(mu-kappa(2)-OTf)(2)(PhCHO)](n), and [UO2(mu-kappa(2)-OTf(kappa(1)-OTf)(PhCHO)(2)](2), which have been fully characterized by NMR, IR, and single-crystal X-ray diffraction.
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Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem