Month: October 2021

Formula: C12H10O. In 2019.0 ACS APPL MATER INTER published article about HYDROGEN-PRODUCTION; 2-DIMENSIONAL SNS2; DOPED SNS2; NANOSHEETS; PERFORMANCE; PHOTOCATALYSTS; DEGRADATION; DEPOSITION; NANOFIBERS; NANOTUBES in [Zuo, Yong; Li, Junshan; Du, Ruifen; Yu, Xiaoting; Xing, Congcong; Cabot, Andreu] IREC, Barcelona 08930, Spain; [Zuo, Yong; Li, Junshan; Du, Ruifen; Yu, Xiaoting] Univ Barcelona, Dept Elect, E-08028 Barcelona, Spain; [Liu, Yongpeng; Yao, Liang; Sivula, Kevin; Guijarro, Nestor] Ecole Polytech Fed Lausanne, Lab Mol Engn Optoelect Nanomat LIMNO, Stn 6, CH-1015 Lausanne, Switzerland; [Zhang, Ting; Arbiol, Jordi] CSIC, ICN2, Campus UAB, Barcelona 08193, Spain; [Zhang, Ting; Arbiol, Jordi] BIST, Campus UAB, Barcelona 08193, Spain; [Arbiol, Jordi; Cabot, Andreu] ICREA, Pg Lluis Co 23, Barcelona 08010, Spain; [Llorca, Jordi] Univ Politecn Cataluna, EEBE, Inst Energy Technol, Dept Chem Engn, Barcelona 08019, Spain; [Llorca, Jordi] Univ Politecn Cataluna, EEBE, Barcelona Res Ctr Multiscale Sci & Engn, Barcelona 08019, Spain in 2019.0, Cited 50.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Tin disulfide (SnS2) is attracting significant interest because of the abundance of its elements and its excellent optoelectronic properties in part related to its layered structure. In this work, we specify the preparation of ultrathin SnS2 nanoplates (NPLs) through a hot-injection solution-based process. Subsequently, Pt was grown on their surface via in situ reduction of a Pt salt. The photoelectrochemical (PEC) performance of such nanoheterostructures as photoanode toward water oxidation was tested afterwards. Optimized SnS2-Pt photoanodes provided significantly higher photocurrent densities than bare SnS2 and SnS2-based photoanodes of previously reported study. Mott-Schottky analysis and PEC impedance spectroscopy (PEIS) were used to analyze in more detail the effect of Pt on the PEC performance. From these analyses, we attribute the enhanced activity of SnS2-Pt photoanodes reported here to a combination of the very thin SnS2 NPLs and the proper electronic contact between Pt nanoparticles (NPs) and SnS2.

About Diphenyl oxide, If you have any questions, you can contact Zuo, Y; Liu, YP; Li, JS; Du, RF; Yu, XT; Xing, CC; Zhang, T; Yao, L; Arbiol, J; Llorca, J; Sivula, K; Guijarro, N; Cabot, A or concate me.. Formula: C12H10O

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Authors Parker, BF; Hosoya, H; Arnold, J; Tsurugi, H; Mashima, K in AMER CHEMICAL SOC published article about O-ACYLATIVE CLEAVAGE; BOND; ACTIVATION; CHLORIDE; LIGANDS; REAGENT; HALIDES in [Parker, Bernard F.; Hosoya, Hiromu; Tsurugi, Hayato; Mashima, Kazushi] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan; [Parker, Bernard F.; Arnold, John] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA in 2019, Cited 34. SDS of cas: 103-50-4. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

alpha-Diimine niobium complexes serve as catalysts for deoxygenation of benzyl ethers by silicon tetrachloride (SiCl4) to cleanly give two equivalents of the corresponding benzyl chlorides, where SiCl4 has the dual function of oxygen scavenger and chloride source with the formation of a silyl ether or silica as the only byproduct. The reaction mechanism has two successive trans-etherification steps that are mediated by the niobium catalyst, first forming one equivalent of benzyl chloride along with the corresponding silyl ether intermediate that undergoes the same reaction pathway to give the second equivalent of benzyl chloride and silyl ether.

About Benzyl ether, If you have any questions, you can contact Parker, BF; Hosoya, H; Arnold, J; Tsurugi, H; Mashima, K or concate me.. SDS of cas: 103-50-4

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I found the field of Environmental Sciences & Ecology very interesting. Saw the article The effect of long-range transport, trophic position and diet specialization on legacy contaminant occurrence in great skuas, Stercorarius skua, breeding across the Northeast Atlantic published in 2019. Quality Control of Diphenyl oxide, Reprint Addresses Borga, K (corresponding author), Univ Oslo, Dept Biosci, Pb 1066, N-0316 Oslo, Norway.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

High levels of halogenated organic contaminants (HOCs) have been found in the marine predatory seabird great skua (Stercorarius skua) from breeding colonies in the Northeastern Atlantic, with large unexplained inter-colony variation. The present study aimed at analyzing if the HOCs occurrence in breeding great skuas in remote colonies was explained by local baseline food web exposure determined by long-range transport, or by ecological factors such as diet specialization and relative trophic position in the breeding area. The occurrence of organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs) was analyzed in plasma of 204 adult great skuas collected over two years (2008 and 2009) and 5 colonies across the North-Atlantic from Shetland to Svalbard. The HOCs levels in plasma ranged across two orders of magnitude, from 40 to 7600 ng/g (wet weight) and differed significantly across the great skua colonies. The variation in contaminant occurrence among colonies did not reflect long-range transport through a latitudinal or remoteness gradient, as the second northernmost colony (Bjornoya), had the highest contaminant concentrations. No latitudinal or remoteness gradient was evident in the contaminant pattern among the colonies. The contaminant levels increased significantly with increasing delta N-15 values, and regurgitated pellets of undigested prey suggested that great skuas with higher delta N-15 values had a higher proportion of bird prey in their diet, mostly seabirds. In contrast, great skuas from colonies with lower delta N-15 and lower contaminant level fed mostly on fish. The enrichment of delta N-13 increased with decreasing delta N-15 and lower contaminant levels. Therefore, individual behavior of great skuas, such as migration strategies and diet specialization, rather than long-range transport and thus baseline food web exposure, explain among and within colony variance in contaminant occurrence. (C) 2018 Elsevier Ltd. All rights reserved.

Quality Control of Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Leat, EHK; Bourgeon, S; Hanssen, SA; Petersen, A; Strom, H; Bjorn, TH; Gabrielsen, GW; Bustnes, JO; Furness, RW; Haarr, A; Borga, K or concate me.

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An article Modulation of J-Aggregation of Nonfullerene Acceptors toward Near-Infrared Absorption and Enhanced Efficiency WOS:000537677300012 published article about ORGANIC SOLAR-CELLS; NON-FULLERENE ACCEPTORS; MORPHOLOGY; PERFORMANCE; POLYMER; DONOR in [Zhang, Xue; Wang, Hui; Li, Donghui; Chen, Mengxue; Mao, Yuchao; Du, Baocai; Zhuang, Yuan; Liu, Dan; Wang, Tao] Wuhan Univ Technol, Sch Mat Sci & Engn, Wuhan 430070, Peoples R China; [Zhang, Xue; Wang, Hui; Li, Donghui; Chen, Mengxue; Mao, Yuchao; Du, Baocai; Zhuang, Yuan; Liu, Dan; Wang, Tao] Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Peoples R China; [Tan, Wenliang; Huang, Wenchao] Monash Univ, Dept Mat Sci & Engn, Clayton, Vic 3800, Australia; [Zhao, Yan] Wuhan Univ Technol, Int Sch Mat Sci & Engn, Wuhan 430070, Peoples R China in 2020.0, Cited 53.0. Name: Diphenyl oxide. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

The molecular aggregation of nonfullerene acceptors (NFA) can significantly affect the light absorption, charge generation, and power conversion efficiency (PCE) of organic solar cells (OSCs). In this work, we demonstrate the regulation of J-aggregation of COi8DFIC NFA toward near- infrared absorption via solvent additives 1,8-diiodooctane (DIO), diphenyl ether (DPE), and 1-chloronaphthalene (CN). Molecular dynamics simulations reveal preferential interaction of DIO with the alkyl side chains of COi8DFIC, endowing side-chains with the flexibility to adjust conformations to promote the formation of A-to-D type J-aggregation among the COi8DFIC backbone, resulting in a significant red-shift of absorbance toward the near-infrared region. The enhanced J-aggregation via pi-pi stacking, evidenced by grazing-incidence wide-angle X-ray scattering, constructs three-dimensional charge transport channels at the molecular level to facilitate charge transport. The presence of 0.5 vol % DIO molecules, which is most effective among all three additives, boosts the maximum achievable PCE of CF cast PTB7-Th:COi8DFIC OSCs from 8.5% to 12.9%. Our results provide a new concept to enhance the efficiency of OSCs via dedicated control of molecular aggregations of nonfullerene acceptors.

Name: Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Zhang, X; Wang, H; Li, DH; Chen, MX; Mao, YC; Du, BC; Zhuang, Y; Tan, WL; Huang, WC; Zhao, Y; Liu, D; Wang, T or concate me.

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Ether – Wikipedia,
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Category: ethers-buliding-blocks. Recently I am researching about CATALYTIC PERFORMANCE; SPATIAL-DISTRIBUTION; ACID SITES; ALKYLATION; BEHAVIOR; POROSITY, Saw an article supported by the Science and Technology Program of Guangzhou, China [201804010172]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21576094, 21576221, 21276052]; Science and Technology Planning Project of Guangdong Province, China [2012A090300006]; National Key Technology RD ProgramNational Key Technology R&D Program [2015BAK45B01]. Published in ELSEVIER in AMSTERDAM ,Authors: Liu, BY; Chen, ZP; Huang, JJ; Chen, HY; Fang, YX. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether

The MFI zeolites with nanosheet assemblies morphology were prepared by a seed-assisted strategy using specially designed bolaform surfactant [C6H13-N+ (CH3)(2)-C6H12-N+ (CH3)(2)-(CH2)(12)-O-(p-C6H4)(2)-O-(CH2)(12)-N+(CH3)(2)-C6H12-N+(CH3)(2)-C6H13] [Br-](4) (C6-12-diphe) as a structure-directing agent. The MFI zeolite nanosheet assemblies were composed of MFI nanosheets with randomly organized structure, exhibiting a narrow mesopore distribution. By tuning the Si/AI ratios of MFI zeolite nanosheet assemblies from 60 to 10, the morphology of resultant zeolites changed from nanosheet stacks to house-of-cards-like structures, and to nanosponges. In addition, the porosity and Bronsted acid/Lewis acid ratio exhibited a parabola-type dependence on the Si/Al ratios of obtained zeolites, indicating that meso-/microporosity and acidity of MFI nanosheet assemblies can be systematically tailored by changing the constituents of zeolites. Catalytic performance of MFI zeolite nanosheet assemblies was investigated in the benzylation of benzyl alcohol with mesitylene. The results revealed that MFI zeolite nanosheet assemblies exhibited extraordinary catalytic activity compared to conventional ZSM-5 zeolite. The conversion of benzyl alcohol and selectivity (1,3,5-trimethyl-2-benzylbenzene vs dibenzyl ether) of zeolite catalysts were linearly dependent on the 81-misted acid/Lewis acid ratio, and they exhibited a parabola-type dependence on the S-ext/S-BET, indicating that a balance between acidity and porosity of zeolites can be realized to modulate the catalytic properties of MFI zeolite nanosheet assemblies guided by C6-12-diphe.

Category: ethers-buliding-blocks. About Benzyl ether, If you have any questions, you can contact Liu, BY; Chen, ZP; Huang, JJ; Chen, HY; Fang, YX or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Quality Control of Diphenyl oxide. I found the field of Environmental Sciences & Ecology very interesting. Saw the article The occurrence of polybrominated diphenyl ether (PBDE) contamination in soil, water/sediment, and air published in 2019.0, Reprint Addresses Wang, YY (corresponding author), Nankai Univ, Tianjin Key Lab Environm Remediat & Pollut Contro, Key Lab Pollut Proc & Environm Criteria, Minist Educ,Coll Environm Sci & Engn, Tianjin 300350, Peoples R China.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide.

As a kind of brominatedflame retardants (BFRs), polybrominated diphenyl ethers (PBDEs) are extensively used in different types of electronic equipment, furniture, plastics, and textiles. PBDEs are ubiquitous environmental contaminants that may impact human health and ecosystems. Here we highlight recent findings on the occurrence, contamination status, and transport of PBDEs in soil, water/sediment, and air. Four aspects are discussed in detail: (1) sources of PBDEs to the environment; (2) occurrence and transport of PBDEs in soil; (3) PBDEs in aquatic ecosystems (water/sediment) and their water-sediment partitioning; and (4) the occurrence of PBDEs in the atmosphere and their gas-particle partitioning. Future prospects for the investigation on PBDEs occurrence are also discussed based on current scientific and practical needs.

Quality Control of Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Wu, ZN; Han, W; Yang, X; Li, Y; Wang, YY or concate me.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Formula: C14H14O. In 2021 CHEM PAP published article about COMMERCIAL ZINC-OXIDE; ONE-POT SYNTHESIS; ACYLATIVE CLEAVAGE; ACID-CHLORIDES; ACYCLIC ETHERS; CYCLIC ETHERS; EFFICIENT; HALIDES; 2-AMINOTHIOPHENES; MILD in [Tang, Yuqi; Yang, Wanfeng; Wang, Wei; Chen, Junqing] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China; [Feng, Chengliang] Jiangsu Coll Engn & Technol, Inst Pharmaceut Engn, Nantong 226000, Jiangsu, Peoples R China; [Ji, Min] Southeast Univ, Sch Biol Sci & Med Engn, Nanjing 211189, Jiangsu, Peoples R China in 2021, Cited 31. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

An efficient method for the synthesis of chloroesters by the reaction of ethers with acyl chlorides catalyzed by nano-ZnO under solvent-free condition at room temperature was described. The method is compatible with a range of ethers including tricyclic ethers, tetracyclic ethers, pentacyclic ethers and hexacyclic ethers and have afforded the products with moderate to good yields. The ZnO could be reused up to three times and the product yield after three cycles is 87%.

Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Tang, YQ; Feng, CL; Yang, WF; Ji, M; Wang, W; Chen, JQ or concate me.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Discovery of Novel and Highly Potent Resorcinol Dibenzyl Ether-Based PD-1/PD-L1 Inhibitors with Improved Drug-like and Pharmacokinetic Properties for Cancer Treatment WOS:000603401900044 published article about SMALL-MOLECULE INHIBITORS; PD-L1 in [Cheng, Binbin; Wang, Wei; Niu, Xiaoge; Ren, Yichang; Liu, Ting; Cao, Hao; Wang, Shuanghu; Tu, Yingfeng; Chen, Jingxuan; Liu, Shuwen; Yang, Xuchao; Chen, Jianjun] Southern Med Univ, Sch Pharmaceut Sci, Guangdong Prov Key Lab New Drug Screening, Guangzhou 510515, Peoples R China in 2020, Cited 19. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Product Details of 103-50-4

A series of programmed cell death-1 (PD-1)/programmed cell death ligand 1 (PD-L1) inhibitors based on the resorcinol diphenyl ether scaffold were discovered by incorporating hydrophilic moieties into the side chain and converting into the corresponding hydrochloride salt. Among these compounds, P18 showed the highest inhibitory activity against PD-1/PD-L1 with an IC50 value of 9.1 nM in a homogeneous time-resolved fluorescence binding assay. Besides, P18 promoted HepG2 cell death dose dependently in a HepG2/PD-L1 and Jurkat/PD-1 coculture cell model. Further, P18 demonstrated significantly higher water solubility (17.61 mg/mL) and improved pharmacokinetics (e.g., t(1/2) of similar to 20 h and oral bioavailability of 12%) than the previous analogues. Moreover, P18 was highly effective in suppressing tumor growth in an immune checkpoint humanized mouse model without apparent toxicity. Collectively, these results suggest that compound P18 represents a promising PD-1/PD-L1 inhibitor worthy of further investigation as a potential anticancer agent.

Product Details of 103-50-4. About Benzyl ether, If you have any questions, you can contact Cheng, BB; Wang, W; Niu, XG; Ren, YC; Liu, T; Cao, H; Wang, SH; Tu, YF; Chen, JX; Liu, SW; Yang, XC; Chen, JJ or concate me.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

COA of Formula: C14H14O. In 2019 ADV MATER published article about TUMOR MICROENVIRONMENT; PHOTODYNAMIC THERAPY; HIGHLY EFFICIENT; NANOSHEETS; SURFACE; AGENT in [Gong, Fei; Cheng, Liang; Yang, Nailin; Feng, Liangzhu; Liu, Zhuang] Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Peoples R China; [Betzer, Oshra; Popovtzer, Rachela] Bar Ilan Univ, Fac Engn, IL-52900 Ramat Gan, Israel; [Betzer, Oshra; Popovtzer, Rachela] Bar Ilan Univ, Inst Nanotechnol & Adv Mat, IL-52900 Ramat Gan, Israel; [Zhou, Qiang; Li, Yonggang; Chen, Ruihua] Soochow Univ, Affiliated Hosp 1, Dept Radiol, Suzhou 215006, Jiangsu, Peoples R China in 2019, Cited 40. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

Sonodynamic therapy (SDT) triggered by ultrasound (US) has attracted increasing attention owing to its abilities to overcome critical limitations including low tissue-penetration depth and phototoxicity in photodynamic therapy. Herein, the design of a new type of sonosensitizer is revealed, namely, ultrasmall oxygen-deficient bimetallic oxide MnWOX nanoparticles, for multimodal imaging-guided enhanced SDT against cancer. As-made MnWOX nanoparticles with poly(ethylene glycol) (PEG) modification show high physiological stability and biocompatibility. Interestingly, such MnWOX-PEG nanoparticles exhibit highly efficient US-triggered production of O-1(2) and center dot OH, higher than that of previously reported sonosensitizers (e.g., protoporphyrin IX and titanium dioxide), because the oxygen-deficient structure of MnWOX serves as an electron trap site to prevent electron-hole recombination. The glutathione depletion capability of MnWOX-PEG can also further favor SDT-triggered cancer cell killing. With efficient tumor homing as illustrated by computer tomography and magnetic resonance imaging, MnWOX-PEG enables effective destruction of mouse tumors under US stimulation. After accomplishing its therapeutic functions, MnWOX-PEG can be metabolized by the mouse body without any long-term toxicity. Herein, a new type of sono-sensitizing agent with high SDT efficacy, multimodal imaging functions, and rapid clearance is presented, an agent which is promising for noninvasive SDT cancer treatment.

COA of Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Gong, F; Cheng, L; Yang, NL; Betzer, O; Feng, LZ; Zhou, Q; Li, YG; Chen, RH; Popovtzer, R; Liu, Z or concate me.

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Recently I am researching about ANTI-MARKOVNIKOV HYDROAMINATION; LIGHT PHOTOREDOX CATALYSIS; METAL-ORGANIC FRAMEWORK; SYNTHETIC APPLICATIONS; C-N; EFFICIENT; ALKENES; AMIDATION; AMINES; BONDS, Saw an article supported by the NSFCNational Natural Science Foundation of China (NSFC) [U1604285, 21772032, 21877206]; PCSIRTProgram for Changjiang Scholars & Innovative Research Team in University (PCSIRT) [IRT1061]; 111 ProjectMinistry of Education, China – 111 Project [D17007]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Gao, WJ; Wan, YM; Zhang, ZG; Wu, H; Liu, TX; Zhang, GS. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide. Safety of Diphenyl oxide

A highly efficient PIFA-mediated Hofmann reaction of o-(pyridin-2-yl)aryl amides has been developed to selectively and rapidly construct various potential photocatalytically active 6H-pyrido[1,2-c]quinazolin-6-one derivatives. The use of a nontoxic and eco-friendly organoiodine reagent, operational simplicity, short reaction time, mild reaction conditions, broad substrate scope, high functional group tolerance, and excellent yields make this protocol very simple, practical, and easy to handle. It provides a feasible platform for developing novel organic fluorophore structures. Preliminary research for this purpose shows that the N-5-methylated pyridoquinazolinone 3a could be used as a photocatalyst in several organic transformations, indicating that it is a very promising lead fluorophore for developing new superior photocatalysts.

Safety of Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Gao, WJ; Wan, YM; Zhang, ZG; Wu, H; Liu, TX; Zhang, GS or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem