Month: October 2021

I found the field of Polymer Science very interesting. Saw the article Two Nanoporous Crystalline Forms of Poly(2,6-dimethyl-1,4-phenylene)oxide and Related Co-Crystalline Forms published in 2019. Computed Properties of C14H14O, Reprint Addresses Rizzo, P (corresponding author), Univ Salerno, Dipartimento Chim & Biol, Via Ponte Don Melillo, I-84084 Fisciano, Italy.; Rizzo, P (corresponding author), Univ Salerno, INSTM Res Unit, Via Ponte Don Melillo, I-84084 Fisciano, Italy.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether

Extensive characterizations, mainly by wide-angle X-ray diffraction (WAXD) and Fourier transform infrared (FTIR) techniques, are reported for co-crystalline (CC) poly(2,6-dimethyl-1,4-phenylene)-oxide (PPO) films with many different low-molecular-mass guest molecules. These characterizations are also reported for the corresponding nanoporous crystalline (NC) phases, as obtained by suitable guest-removal procedures. Two well-separated NC forms, hereafter named alpha and beta, are obtained by guest removal from two well-separated groups of CC forms. alpha and beta NC forms can be easily recognized by reflections in WAXD patterns as well as by suitable FTIR crystalline peaks. Density and degree of crystallinity measurements confirm that both NC phases exhibit a density definitely smaller than for the amorphous phase (rho(am) = 1.04 g/cm(3) rho(beta) = 0.95 g/cm(3) > rho(alpha) = 0.93 g/cm(3)). Density functional theory calculations combined with geometrical analysis on PPO model systems indicate conformations suitable to fit the observed chain periodicities of the two crystalline forms (c = 5.28 and 5.47 angstrom, for alpha and beta NC forms, respectively).

About Benzyl ether, If you have any questions, you can contact Nagendra, B; Cozzolino, A; Daniel, C; Rizzo, P; Guerra, G; Auriemma, F; De Rosa, C; D’Alterio, MC; Tarallo, O; Nuzzo, A or concate me.. Computed Properties of C14H14O

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Application In Synthesis of Diphenyl oxide. Authors Wang, Q; Xiao, J; Su, YH; Huang, JW; Li, JH; Qiu, LG; Zhan, MX; He, X; Yuan, WZ; Li, Y in ROYAL SOC CHEMISTRY published article about in [Wang, Qian; Xiao, Jing; Su, Yanhong; Huang, Jianwen; Li, Jihua; Qiu, Lige; Zhan, Meixiao; He, Xu; Li, Yong] Jinan Univ, Zhuhai Hosp, Zhuhai Peoples Hosp, Zhuhai Intervent Med Ctr,Zhuhai Precis Med Ctr, Zhuhai 519000, Guangdong, Peoples R China; [Wang, Qian; Yuan, Weizhong] Tongji Univ, Sch Mat Sci & Engn, Shanghai 201804, Peoples R China in 2021.0, Cited 58.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Amphiphilic thermoresponsive block helical poly(phenyl isocyanide) was synthesized by the polymerization of phenyl isocyanide using a Pd(ii) complex catalyst as an initiator. The polymer could self-assemble into spherical micelles. The lower critical solution temperature (LCST) of the micelle solution was adjusted by changing the molar ratio of the hydrophobic segment to the hydrophilic segment and finally optimized to be 41 degrees C at a molar ratio of 1 : 2. After loading Fe3O4 nanoparticles, the magnetic complex micelles were prepared. The magnetic complex micelles demonstrated reversible thermoresponsiveness and obvious magnetic hyperthermia. Cell viability measurements indicated that the nanomaterials were well-biocompatible and nontoxic. The magnetic complex micelles could be used as nanocarriers to achieve controlled release of doxorubicin (DOX) by altering the temperature. Intracellular experiments demonstrated that the magnetic complex micelles showed excellent anticancer synergistic thermo-chemotherapy performance under an alternating magnetic field (AMF) owing to magnetic hyperthermia from micelle-loaded Fe3O4 nanoparticles and effective drug release due to the morphology change of thermoresponsive poly(phenyl isocyanide)s.

About Diphenyl oxide, If you have any questions, you can contact Wang, Q; Xiao, J; Su, YH; Huang, JW; Li, JH; Qiu, LG; Zhan, MX; He, X; Yuan, WZ; Li, Y or concate me.. Application In Synthesis of Diphenyl oxide

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Authors Ashraf, MA; Liu, ZL; Peng, WX; Zhou, L in SPRINGER published article about CROSS-COUPLING REACTION; LIGAND-FREE; C-S; ONE-POT; ODORLESS SYNTHESIS; HETEROGENEOUS NANOCATALYST; TRIPHENYLTIN CHLORIDE; DIARYL SULFIDES; O-ARYLATION; HALIDES in [Ashraf, Muhammad Ageel; Peng, Wan-Xi] Henan Agr Univ, Sch Forestry, Zhengzhou 450002, Henan, Peoples R China; [Ashraf, Muhammad Ageel] Univ Malaya, Fac Sci, Dept Geol, Kuala Lumpur 50603, Malaysia; [Liu, Zhenling] Henan Univ Technol, Sch Management, Zhengzhou 450001, Henan, Peoples R China; [Zhou, Liang] Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Guizhou, Peoples R China in 2020.0, Cited 65.0. Formula: C12H10O. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

In the present study, copper complex supported on surface-modified Fe3O4/SiO2 nanoparticles (Fe3O4@SiO2-Glycerole-Cu(II)) was successfully fabricated and characterized by fourier transform infrared spectroscopy (FT-IR), thermal gravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray mapping, energy-dispersive X-ray spectroscopy (EDS), inductively coupled plasma optical emission spectroscopy (ICP-OES), N-2 adsorption and desorption (BET) and Vibrating Sample Magnetometer (VSM) techniques. This magnetic nanocatalyst utilized as an effective catalyst for the C-S and C-O cross-coupling reactions of aryl halides with thiourea and phenol. The catalyst could be quickly and completely recovered using an external magnetic field and reused for six reaction cycles without significant change in catalytic activity. [GRAPHICS] .

Formula: C12H10O. About Diphenyl oxide, If you have any questions, you can contact Ashraf, MA; Liu, ZL; Peng, WX; Zhou, L or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

In 2020 POLYMER published article about SYNDIOTACTIC POLYSTYRENE; GAS SORPTION; POLY(2,6-DIMETHYL-1,4-PHENYLENE OXIDE); AMORPHOUS PHASES; SINGLE-CRYSTALS; X-RAY; TRANSPORT; FILMS; MEMBRANES; DELTA in [Guerra, Gaetano] Univ Salerno, Dipartimento Chim & Biol, Via Giovanni Paolo II 132, I-84084 Fisciano, Italy; Univ Salerno, INSTM Res Unit, Via Giovanni Paolo II 132, I-84084 Fisciano, Italy in 2020, Cited 49. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Application In Synthesis of Benzyl ether

The stability of a and beta nanoporous-crystalline (NC) forms of Poly(2,6-dimethyl-1,4-phenylene) oxide (PPO), in the presence of guest molecules leading to crystallization in a and beta-form (alpha and beta-guests), is explored. Sorption of liquid guests at 30 degrees C and 60 degrees C is studied both for NC films and NC aerogels. WAXD and FTIR characterizations show that, for all considered conditions, NC alpha-phases after guest sorption/desorption remain unaltered. NC beta-phases, on the contrary, after alpha-guest sorption can be transformed in co-crystalline (CC) alpha-phases that after guest desorption are transformed in NC alpha-phases. All conducted experiments also show that possible planar orientations of NC films (c//or c perpendicular to orientations) remain essentially unaltered, after sorption of all considered guest molecules. The presently discovered beta ->alpha transition constitutes a route to obtain unoriented alpha-form films, which till now were not available by known preparation procedures.

Application In Synthesis of Benzyl ether. About Benzyl ether, If you have any questions, you can contact Nagendra, B; Cozzolino, A; Golla, M; Daniel, C; Rizzo, P; Guerra, G or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recommanded Product: Diphenyl oxide. I found the field of Engineering; Environmental Sciences & Ecology very interesting. Saw the article A novel management strategy for removal and degradation of polybrominated diphenyl ethers (PBDEs) in waste printed circuit boards published in 2019.0, Reprint Addresses Xiu, FR (corresponding author), Xian Univ Sci & Technol, Coll Geol & Environm, Xian 710054, Shaanxi, Peoples R China.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide.

Waste printed circuit boards (PCBs) contain a high level of brominated flame retardants (BFRs), among which polybrominated biphenyl ethers (PBDEs) are the most widely used additive BFRs. PBDEs are considered to be a type of persistent organic pollutants (POPS). The efficient removal/degradation of PBDEs in waste PCBs is an urgent problem in electronic waste treatment, but the degradation of PBDEs is a great challenge due to their extreme stability and persistence in nature. In this study, a novel management strategy was developed for removal and degradation of PBDEs in waste PCBs by using a simple subcritical methanol (SubCM) process. The results showed that reaction temperature, residence time, solid-to-liquid ratio, and additive NaOH are key factors influencing the removal of PBDEs from waste PCBs. Under optimal conditions (200 degrees C, 60 min, 1:20 g/mL), the removal efficiency of Sigma(8) PBDEs from waste PCBs could reach 91.3% and 98.8% for the proposed process of SubCM and SubCM + NaOH, respectively. When the temperature is below 200 degrees C, highly brominated PBDEs congeners in waste PCBs were degraded into 2,’3,4′,6-Tetrabromodiphenyl ether (BDE71) and 2,4,4′-Tribromodiphenyl ether (BDE28) after SubCM treatment. 4-Bromophenyl ether (BDE4) and diphenyl ether were generated by the further debromination of BDE71 and BDE28 with the increase of treatment temperature. The debromination temperature of PBDEs congeners in SubCM could be markedly lowered by adding 4 g/L of NaOH. The complete debromination of PBDEs congeners in waste PCBs could be achieved at 300 degrees C and 250 degrees C for the developed process of SubCM and SubCM + NaOH, respectively. (C) 2019 Elsevier Ltd. All rights reserved.

About Diphenyl oxide, If you have any questions, you can contact Xiu, FR; Yu, X; Qi, YY; Li, YF; Lu, YW; Wang, YX; He, JH; Zhou, K; Song, ZQ; Gao, X or concate me.. Recommanded Product: Diphenyl oxide

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Authors Woo, S; Nam, D; Chang, W; Ko, Y; Lee, S; Song, Y; Yeom, B; Moon, JH; Lee, SW; Cho, J in WILEY-V C H VERLAG GMBH published article about in [Woo, Seunghui; Nam, Donghyeon; Chang, Woojae; Ko, Younji; Lee, Seokmin; Song, Yongkwon; Cho, Jinhan] Korea Univ, Dept Chem & Biol Engn, 145 Anam Ro, Seoul 02841, South Korea; [Yeom, Bongjun] Hanyang Univ, Dept Chem Engn, 222 Wangsimni Ro, Seoul 04763, South Korea; [Moon, Jun Hyuk] Sogang Univ, Dept Chem & Biomol Engn, Baekbeom Ro 35, Seoul 04107, South Korea; [Lee, Seung Woo] Georgia Inst Technol, George W Woodruff Sch Mech Engn, North Ave NW, Atlanta, GA 30332 USA; [Cho, Jinhan] Korea Univ, KU KIST Grad Sch Converging Sci & Technol, 145 Anam Ro, Seoul 02841, South Korea in 2021, Cited 61. Computed Properties of C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Electrical conductivity, mechanical flexibility, and large electroactive surface areas are the most important factors in determining the performance of various flexible electrodes in energy storage devices. Herein, a layer-by-layer (LbL) assembly-induced metal electrodeposition approach is introduced to prepare a variety of highly porous 3D-current collectors with high flexibility, metallic conductivity, and large surface area. In this study, a few metal nanoparticle (NP) layers are LbL-assembled onto insulating paper for the preparation of conductive paper. Subsequent Ni electroplating of the metal NP-coated substrates reduces the sheet resistance from approximate to 10(3) to <0.1 omega sq(-1) while maintaining the porous structure of the pristine paper. Particularly, this approach is completely compatible with commercial electroplating processes, and thus can be directly extended to electroplating applications using a variety of other metals in addition to Ni. After depositing high-energy MnO NPs onto Ni-electroplated papers, the areal capacitance increases from 68 to 811 mF cm(-2) as the mass loading of MnO NPs increases from 0.16 to 4.31 mg cm(-2). When metal NPs are periodically LbL-assembled with the MnO NPs, the areal capacitance increases to 1710 mF cm(-2). Computed Properties of C14H14O. About Benzyl ether, If you have any questions, you can contact Woo, S; Nam, D; Chang, W; Ko, Y; Lee, S; Song, Y; Yeom, B; Moon, JH; Lee, SW; Cho, J or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Product Details of 101-84-8. Ashraf, MA; Liu, ZL; Peng, WX; Zhou, L in [Ashraf, Muhammad Ageel; Peng, Wan-Xi] Henan Agr Univ, Sch Forestry, Zhengzhou 450002, Henan, Peoples R China; [Ashraf, Muhammad Ageel] Univ Malaya, Fac Sci, Dept Geol, Kuala Lumpur 50603, Malaysia; [Liu, Zhenling] Henan Univ Technol, Sch Management, Zhengzhou 450001, Henan, Peoples R China; [Zhou, Liang] Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Guizhou, Peoples R China published Glycerol Cu(II) Complex Supported on Fe3O4 Magnetic Nanoparticles: A New and Highly Efficient Reusable Catalyst for the Formation of Aryl-Sulfur and Aryl-Oxygen Bonds in 2020.0, Cited 65.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

In the present study, copper complex supported on surface-modified Fe3O4/SiO2 nanoparticles (Fe3O4@SiO2-Glycerole-Cu(II)) was successfully fabricated and characterized by fourier transform infrared spectroscopy (FT-IR), thermal gravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray mapping, energy-dispersive X-ray spectroscopy (EDS), inductively coupled plasma optical emission spectroscopy (ICP-OES), N-2 adsorption and desorption (BET) and Vibrating Sample Magnetometer (VSM) techniques. This magnetic nanocatalyst utilized as an effective catalyst for the C-S and C-O cross-coupling reactions of aryl halides with thiourea and phenol. The catalyst could be quickly and completely recovered using an external magnetic field and reused for six reaction cycles without significant change in catalytic activity. [GRAPHICS] .

About Diphenyl oxide, If you have any questions, you can contact Ashraf, MA; Liu, ZL; Peng, WX; Zhou, L or concate me.. Product Details of 101-84-8

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recommanded Product: Diphenyl oxide. Authors Zakhtser, A; Naitabdi, A; Benbalagh, R; Rochet, F; Salzemann, C; Petit, C; Giorgio, S in AMER CHEMICAL SOC published article about in [Zakhtser, Alter; Naitabdi, Ahmed; Benbalagh, Rabah; Rochet, Francois; Salzemann, Caroline; Petit, Christophe] Sorbonne Univ, F-75005 Paris, France; [Giorgio, Suzanne] Aix Marseille Univ, F-13288 Marseille, France in 2021, Cited 65. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

We report on the shape, composition (from Pt95Zn5 to Pt77Zn23), and surface chemistry of Pt-Zn nanoparticles obtained by reduction of precursors M2+(acac) (-)(2) (M2+: Pt2+ and Zn2+) in oleylamine, which serves as both solvent and ligand. We show first that the addition of phenyl ether or benzyl ether determines the composition and shape of the nanoparticles, which point to an adsorbate-controlled synthesis. The organic (ligand)/inorganic (nanoparticles) interface is characterized on the structural and chemical level. We observe that the particles, after washing with ethanol, are coated with oleylamine and the oxidation products of the latter, namely, an aldimine and a nitrile. After exposure to air, the particles oxidize, covering themselves with a few monolayer thick ZnO film, which is certainly discontinuous when the particles are low in zinc. Pt-Zn particles are unstable and prone to losing Zn. We have strong indications that the driving force is the preferential oxidation of the less noble metal. Finally, we show that adsorption of CO on the surface of nanoparticles modifies the oxidation state of amine ligands and attribute it to the displacement of hydrogen adsorbed on Pt. All the structural and chemical information provided by the combination of electron microscopy and X-ray photoelectron spectroscopy allows us to give a fairly accurate picture of the surface of nanoparticles and to better understand why Pt-Zn alloys are efficient in certain electrocatalytic reactions such as the oxidation of methanol.

Recommanded Product: Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Zakhtser, A; Naitabdi, A; Benbalagh, R; Rochet, F; Salzemann, C; Petit, C; Giorgio, S or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Formula: C12H10O. Gassel, M; Rochman, CM in [Gassel, Margy] Calif Environm Protect Agcy, Off Environm Hlth Hazard Assessment, Sacramento, CA 95812 USA; [Rochman, Chelsea M.] Univ Toronto, Dept Ecol & Evolutionary Biol, Toronto, ON M5S 3B2, Canada published The complex issue of chemicals and microplastic pollution: A case study in North Pacific lanternfish in 2019.0, Cited 62.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Marine plastic debris, including microplastics (<5 mm in size), comprises a suite of chemical ingredients and sorbed chemical contaminants. Thus, microplastics are a potential, and debated, source of anthropogenic chemicals for bioaccumulation and biomagnification. Several studies have investigated the role of microplastics as a vector of contaminants to marine organisms via modeling exercises, laboratory experiments, and field studies. Here, we examined relationships among chemical contaminants and microplastics in lanternfish (family Myctophidae), an important link in marine food webs, from the North Pacific Ocean as a case study from the field. We compared the body burden of several chemical groups (bisphenol A [BPA], nonylphenol [4-NP], octylphenol [4n-OP], alkylphenol ethoxylates [APEs], pesticides, polychlorinated biphenyls [PCBs], and polybrominated diphenyl ethers [PBDEs]) in fish caught within and outside the North Pacific Subtropical Gyre where plastic is known to accumulate. We also tested whether there was a relationship between chemical concentrations in fish and plastic density at each sampling location. Mean concentrations of common plastic constituents (BPA, 4-NP, 4n-OP, APEs, and total PBDEs) were comparable between myctophids collected within and outside the North Pacific Gyre. Pesticides were higher in lanternfish caught outside the gyre and were associated with lower plastic density. Total PCBs were also higher in fish outside the gyre. In contrast, lower chlorinated PCB congeners were higher in fish residing in the accumulation zone and were correlated with higher plastic density. This finding is consistent with other studies demonstrating an association between lower chlorinated PCBs and plastics in biota and suggests that microplastic may be a transport mechanism for some chemicals in nature. (C) 2019 Elsevier Ltd. All rights reserved. Formula: C12H10O. About Diphenyl oxide, If you have any questions, you can contact Gassel, M; Rochman, CM or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

I found the field of Environmental Sciences & Ecology very interesting. Saw the article Comparative evaluation of river chemical status based on WFD methodology and CCME water quality index published in 2020.0. Product Details of 101-84-8, Reprint Addresses Gikas, GD (corresponding author), Democritus Univ Thrace, Sch Engn, Dept Environm Engn, Lab Ecol Engn & Technol, Xanthi 67100, Greece.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

The Water Framework Directive (WFD) methodology, proposed by the Ministry of Environment and Energy of Greece (WFD-MEEG), and the Canadian Council of Ministers of Environment Water Quality Index (CCME-WQI) are comparatively applied to evaluate the chemical status of a major transboundary river. Water quality parameters were monitored at 11 sites along the main stream of the river and its main tributaries, and at five sites in the reservoirs, on a monthly frequency, in the period from May 2008 to May 2009. Water temperature (T), dissolved oxygen (DO), pH, and electrical conductivity (EC) were measured in-situ, while water samples were collected for the determination of total suspended solids (TSS), biochemical oxygen demand (BOD), chemical oxygen demand (COD), nitrite-, nitrate- and ammonium-nitrogen, total Kjeldahl nitrogen (TKN), ortho-phosphates (OP), total phosphorus (TP), and chlorophyll-a (Chl-a). The water samples were also analyzed for the determination of seven heavy metals (i.e., Cd, Pb, Hg, Ni, Cr, Cu, Zn) and 33 priority substances, as listed in Annex II of EU Directive 2008/105/EC. The results showed that the physicochemical parameters (i.e., T. DO, pH, EC, inorganic nitrogen, MN, OP, TP, TSS, and Chia) were within the natural range. The mean concentration of the measured heavy metals did not exceed the limits set by WHO (2003, 2017) for drinking water. Regarding the priority substances, some of them ( i.e., anthracene, fluoranthene, and polyaromatic hydrocarbons) were measured in various stations at higher concentrations than the Annual Average Environmental Quality Standards (AA-EQS). Based on the WFD-MEEG methodology, the river water was in the ‘good’ quality class, while according to CCME-WQI the river quality ranged from ‘marginal’ to ‘good’ category. It seems that CCME-WQI is stricter than WFD-MEEG but could be a WQI appropriate for use. (C) 2020 Elsevier B.V. All rights reserved.

Product Details of 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Gikas, GD; Sylaios, GK; Tsihrintzis, VA; Konstantinou, IK; Albanis, T; Boskidis, I or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem