An article Ni-Catalyzed reductive amination of phenols with ammonia or amines into cyclohexylamines WOS:000529203600006 published article about SELECTIVE HYDROGENATION; NITROARENE HYDROGENATION; NICKEL-CATALYST; ARYL ETHERS; CONVERSION; LIGNIN; HYDROGENOLYSIS; CYCLOHEXANONE; ALKYLATION; ALCOHOLS in [Cuypers, Thomas; Morias, Thomas; Windels, Simon; Marquez, Carlos; Van Goethem, Cedric; Vankelecom, Ivo; De Vos, Dirk E.] Univ Leuven, KU Leuven, Ctr Membrane Separat Adsorpt Catalysis & Spect cM, Celestijnenlaan 200F,Post Box 2461, B-3001 Heverlee, Belgium in 2020.0, Cited 69.0. Quality Control of Diphenyl oxide. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8
Phenol and its derivatives, which naturally occur in lignocellulose, can be considered as a renewable feedstock not only for aromatic, but also for alicyclic compounds, such as primary and N-substituted cyclohexylamines. So far, the latter are mostly produced from non-renewable starting materials like benzene via problematic nitration/reduction or cross-coupling routes. Herein, an efficient reductive amination of phenol with ammonia or amines is demonstrated, for the first time without the need for rare and expensive noble metals and without using any additives. Various supported Ni catalysts were screened and we elucidated the influence of the key parameters, including the acid-base properties of the supporting material. Acquired knowledge was then applied to different phenol-ammonia/amine combinations, resulting in the synthesis of various primary, secondary and tertiary cyclohexylamines in fair to very high yields.
About Diphenyl oxide, If you have any questions, you can contact Cuypers, T; Morias, T; Windels, S; Marquez, C; Van Goethem, C; Vankelecom, I; De Vos, DE or concate me.. Quality Control of Diphenyl oxide
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