Recently I am researching about TEMPERATURE-PROGRAMMED DESORPTION; MODEL COMPOUNDS; CATALYTIC HYDRODEOXYGENATION; BOND-CLEAVAGE; AROMATIC-HYDROCARBONS; HY ZEOLITE; HYDROCRACKING; OIL; HYDROGENOLYSIS; MECHANISMS, Saw an article supported by the Swedish Energy AgencySwedish Energy Agency [2016-08330]; FormasSwedish Research Council Formas [2017-01392]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Salam, MA; Cheah, YW; Ho, PH; Olsson, L; Creaser, D. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide. Name: Diphenyl oxide
Sulfides of NiMo over a series of commercial ultra-stable Y zeolites were studied in an autoclave reactor to elucidate the effect of silica/alumina ratio (SAR = 12, 30, and 80) on the cleavage of etheric C-O (beta-O-4) and C-C (both sp(3)-sp(2) and sp(2)-sp(2)) linkages present in native/technical lignin and lignin derived bio-oils. 2-Phenethyl phenyl ether (PPE), 4,4-dihydroxydiphenylmethane (DHDPM), and 2-phenylphenol, (2PP) were examined as model dimers at 345 degrees C and 50 bar of total pressure using dodecane as the solvent. The etheric C-O hydrogenolysis activity was found to be in the order NiMoY30 > NiMoY12 > NiMoY80, despite a high initial rate of C-O cleavage over NiMoY12 owing to its high acid density. A high degree of hydrodeoxygenation (HDO) and hydrocracking reactions were observed with NiMoY30 yielding >80% of deoxygenated products of which similar to 58% are benzene, toluene, and ethylbenzenes. A similar experiment with DHDPM showed the rapid cleavage of the methylene-linked C-C dimer (sp(3)-sp(2)) to phenols and cresols even with the low acid density (high SAR) catalyst, NiMoY80. Direct hydrocracking of the recalcitrant 5-5 ‘ linkage in 2PP is very slow, however, it cleaved via a cascade of HDO, ring-hydrogenation, and hydrocracking reactions. A high degree of hydrogenolysis and hydrocracking occurs over NiMoY30 due to suitable balance between acidity and pore accessibility, enhanced proximity between acidic and deoxygenation sites leading to a slightly higher dispersion of Ni promoted MoS2 crystallites. Overall, the product spectrum consisted of a high yield of deoxygenated products. The carbon content on the recovered catalyst was in the range of 3-7 wt%. These results pave the way for effective catalysts to break recalcitrant linkages present in lignin to obtain a hydrocarbon-rich liquid transportation fuel. An experiment with Kraft lignin over NiMoY30 shows good selectivity for deoxygenated aromatics and cycloalkanes in the liquid phase.
Name: Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Salam, MA; Cheah, YW; Ho, PH; Olsson, L; Creaser, D or concate me.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem