SDS of cas: 103-50-4. I found the field of Chemistry; Science & Technology – Other Topics; Materials Science; Physics very interesting. Saw the article Metal-Support Cooperative Effects in Au/VPO for the Aerobic Oxidation of Benzyl Alcohol to Benzyl Benzoate published in 2019, Reprint Addresses Villa, A (corresponding author), Univ Milan, Dipartimento Chim, Via C Golgi 19, I-20133 Milan, Italy.; Dimitratos, N (corresponding author), ALMA MATER STUDIORUM Univ Bologna, Dipartimento Chim Ind & Mat, Viale Risorgimento 4, I-40136 Bologna, Italy.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether.
This paper studies the cooperative effect of Au nanoparticles deposited on vanadyl pyrophosphate oxide (VPO) in the liquid phase oxidation of benzyl alcohol. VPO was prepared using the classical method by thermally treating VOHPO4 center dot 0.5H(2)O precursor in reacting atmosphere at 420 degrees C for a period of 72 h. Au nanoparticles were deposited by incipient wetness method. The catalysts were characterized by means of XRD, TEM, XPS and Raman. The bulk VPO catalyst contains vanadyl pyrophosphate phase ((VO)(2)P2O7), and a small amount of VOPO4. The catalytic system exhibits a high activity in the base-free liquid phase oxidation of alcohols compared to Au on activated carbon, classic catalyst used for this type of reaction. Au/VPO showed a high peculiar selectivity to benzyl benzoate (76%), an important product used in the pharmaceutical and perfume industries. This behavior might be ascribed to the presence of strong acid sites of VPO, as determined by liquid phase titration. Stability tests performed on Au/VPO showed a deactivation of 10% after the first run, but a constant conversion along the following five cycles. This phenomenon can be attributed to the increase of mean Au particle size (from 19.1 to 23.4 nm) after recycling tests as well as the partial leaching of Au and V in the reaction media. Moreover, XRD evidenced a modification in the VPO structure with the partial formation of VOHPO4 center dot 0.5H(2)O phase.
SDS of cas: 103-50-4. About Benzyl ether, If you have any questions, you can contact Campisi, S; Ferri, M; Chan-Thaw, CE; Trujillo, FJS; Motta, D; Tabanelli, T; Dimitratos, N; Villa, A or concate me.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem