Recently I am researching about C-O BOND; SECONDARY ALCOHOLS; DIRECT AMINATION; MECHANISM; ETHERS; CLEAVAGE; HYDROAMINATION; DEHYDRATION; HYDROLYSIS; COUPLINGS, Saw an article supported by the Solvay; University of Lille; Chevreul Institute [FR 2638]; Ministere de l’Enseignement Superieur, de la Recherche et de l’Innovation; Hauts-de-France RegionRegion Hauts-de-France; FEDEREuropean Commission. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Niu, F; Wang, QY; Yan, Z; Kusema, BT; Khodakov, AY; Ordomsky, VV. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether. COA of Formula: C14H14O
Catalytic N-alkylation of amines by alcohols to produce desired amines is an important catalytic reaction in industry. Various noble-metal-based homogeneous and heterogeneous catalysts have been reported for this process. The development of cheap non-noble-metal heterogeneous catalysts for the N-alkylation reaction would be highly desirable. Hereby, we propose the N-alkylation of amines by alcohols over a cheap and efficient heterogeneous catalyst-titanium hydroxide. This catalyst provides a selectivity higher than 90% to secondary amines for functionalized aromatic and aliphatic alcohols and amines with high catalytic activity and stability. Mild Bronsted acidity formed by the continuous rehydration of Lewis acidity excludes the side reactions and deactivation by adsorbed species. The mechanism of the reaction involves dehydration of alcohols to ethers with subsequent C-O bond cleavage by amine with the formation of secondary amine and recovery of alcohol.
COA of Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Niu, F; Wang, QY; Yan, Z; Kusema, BT; Khodakov, AY; Ordomsky, VV or concate me.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem