Recommanded Product: Diphenyl oxide. Yang, SQ; Lu, XM; Yao, HY; Xin, JY; Xu, JL; Kang, Y; Yang, YQ; Cai, GM; Zhang, SJ in [Yang, Shaoqi; Lu, Xingmei; Yao, Haoyu; Xin, Jiayu; Xu, Junli; Kang, Ying; Yang, Yongqing; Cai, Guangming; Zhang, Suojiang] Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,CAS Key La, Beijing 100190, Peoples R China; [Yang, Shaoqi; Lu, Xingmei; Zhang, Suojiang] Univ Chinese Acad Sci, Sino Danish Coll, Beijing 100049, Peoples R China published Efficient hydrodeoxygenation of lignin-derived phenols and dimeric ethers with synergistic [Bmim]PF6-Ru/SBA-15 catalysis under acid free conditions in 2019.0, Cited 52.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.
Selective catalytic hydrotreatment of lignin-derived phenols and dimeric ethers into alkanes is crucial for utilization of lignin and its fragments. Herein, we developed an efficient catalytic system with well-dispersed metal nanoparticles supported on SBA-15 synergistic with an ionic liquid. The catalytic system could catalyze the hydrodeoxygenation (HDO) of various monomeric and dimeric lignin-derived phenols into the corresponding alkanes under acid free conditions. The synergistic [Bmim]PF6-Ru/SBA-15 (1-butyl-3-methylimidazolium hexafluorophosphate) catalysis exhibited the best HDO activity for ligninderived phenols and dimeric ethers with >99.0% conversion and maximum > 98.0% selectivity of the corresponding alkanes. The yield of cyclohexane from diphenyl ether was 97.7% with 100% conversion under 2 MPa H-2 at 130 degrees C for 6 h. The mechanism investigation confirmed that the Ru/SBA-15 catalyst and the anion of [Bmim] PF6 played crucial roles in the hydrogenation process and deoxidization process, respectively. The catalytic system was reused six times for HDO of diphenyl ether to test its stability.
About Diphenyl oxide, If you have any questions, you can contact Yang, SQ; Lu, XM; Yao, HY; Xin, JY; Xu, JL; Kang, Y; Yang, YQ; Cai, GM; Zhang, SJ or concate me.. Recommanded Product: Diphenyl oxide
Reference:
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