Safety of Diphenyl oxide. Recently I am researching about MIZOROKI-HECK; SUZUKI; NANOPARTICLES; STABILITY; PATHWAYS, Saw an article supported by the Special Scientific Research Project of Shaanxi Education Department [19JK0904]; Science Research Foundation of Xijing University [XJ18T03, XJ18B05]; Youth Innovation Team of Shaanxi Universities. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Zhu, YF; Xu, GY; Kazemnejadi, M. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide
Bis(NHC)-Pd-catalyzed competitive asymmetrical C-C*C-C, C-C*C-O, C-C*C-N, and O-C*C-N cross-coupling reactions were performed via the one-pot strategy in the presence of a new ionic liquid, which played the roles of solvent, base, and ligand simultaneously. The ionic liquid was prepared based on a methyl imidazolium moiety with hydroxyl counter anions via a Hofmann elimination on a 1,3,5-triazine framework (TAIm[OH]). Pd ions could be efficiently coordinated through the bis(NHC)-ligand moiety in the ionic liquid. Based on differences in the competitive kinetics of C-C cross-coupling reactions (Heck, Suzuki, and Sonogashira) with C-N and C-O cross-coupling reactions, and also differences in the kinetics of aryl halides, the coupling reactions could be selectively performed with a low amount of by-products. The competitive cross-coupling reactions were thus performed with high selectivity under mild reaction conditions.
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Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem