An article Catalytic Hydroconversion of Ethanol-Soluble Portion from the Ethanolysis of Hecaogou Subbituminous Coal Extraction Residue to Clean Liquid Fuel over a Zeolite Y/ZSM-5 Composite Zeolite-Supported Nickel Catalyst WOS:000526324100074 published article about ZSM-5 ZEOLITE; Y ZEOLITE; LIGNITE; HYDROGENATION; GUAIACOL; HYDRODEOXYGENATION; HYDROGENOLYSIS; ACCESSIBILITY; SITES; NI in [Kang, Yu-Hong; Wei, Xian-Yong; Liu, Guang-Hui; Ma, Xiang-Rong; Gao, Yong; Li, Xiao; Li, Yan Jun; Zong, Zhi-Min] China Univ Min & Technol, Minist Educ, Key Lab Coal Proc & Efficient Utilizat, Xuzhou 221116, Jiangsu, Peoples R China; [Kang, Yu-Hong; Wei, Xian-Yong; Ma, Xiang-Rong; Gao, Yong; Li, Xiao; Li, Yan Jun; Ma, Ya-Jun; Yan, Long] Yulin Univ, Shaanxi Key Lab Low Metamorph Coal Clean Utilizat, Sch Chem & Chem Engn, Yulin 71900, Shaanxi, Peoples R China in 2020, Cited 29. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. COA of Formula: C14H14O
A novel and highly active zeolite Y/ZSM-5 composite zeolite (CZ)-supported nickel catalyst (Ni/CZ with 10% of Ni loading) was prepared by modified deposition-precipitation to uniformly disperse Ni nanoparticles (NNPs) onto CZ. Hecaogou subbituminous coal was exhaustively extracted with isometric carbon disulfide/acetone mixed solvent to afford the extractable portion and inextractable portion (IEP). Ethanol-soluble portion (ESP) was obtained by ethanolyzing the IEP at 300 degrees C and subjected to catalytic hydroconversion (CHC) over Ni-10%/CZ at 160 degrees C to afford catalytically hydroconverted ESP (CHCESP). Both ESP and CHCESP were analyzed with a Fourier transform infrared spectrometer, gas chromatograph/mass spectrometer (GC/MS), and quadrupole exactive orbitrap mass spectrometer. The results show that the relative contents (RCs) of both chain alkanes and hydroarenes in CHCESP are significantly higher than those in ESP and cyclanes and alkenes were only detected in CHCESP, while the RCs of both arenes and oxygen-containing organic compounds in CHCESP are much lower than those in ESP and nitrogen- and/or sulfur-containing organic compounds were only detected in ESP with GC/MS. According to the CHC of oxybis(methylene)dibenzene (OBMDB), Ni-10%/CZ can effectively activate H-2 to biatomic active hydrogen (H center dot center dot center dot H) and the resulting H center dot center dot center dot H was heterolytically split into an immobile H- attached on Ni/CZ and a mobile H+. H+ transfers to an oxygen atom (OA) in OBMDB and cleaves the C-O bridged bond to produce phenylmethanol (PM) and benzylium, followed by H- abstraction from the Ni/CZ surface by benzylium to form toluene. H+ transfer to the OA in PM also leads to the cleavage of the C-O bond in PM to produce H2O and benzylium, which abstracts H- from the Ni/CZ surface to yield toluene. H center dot center dot center dot H transfer to the benzene ring in toluene generates methylcyclohexane. Therefore, Ni-10%/CZ catalyzes both H+ and H center dot center dot center dot H transfer. In addition, it proved to be stable for the CHC of OBMDB after 3 cycles.
COA of Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Kang, YH; Wei, XY; Liu, GH; Ma, XR; Gao, Y; Li, X; Li, YJ; Ma, YJ; Yan, L; Zong, ZM or concate me.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem