Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Masuyama, Y, once mentioned the application of 60166-93-0, Name is Iopamidol, molecular formula is C17H22I3N3O8, molecular weight is 777.09, MDL number is MFCD00867931, category is iodides-buliding-blocks. Now introduce a scientific discovery about this category, Quality Control of Iopamidol.
Carbonyl allylations by allylic chlorides utilizing a reduction of tin(IV) iodide to triiodostannate(II) species with iodide sources
Carbonyl allylations by allylic chlorides either with tin(IV) iodide and tetrabutylammonium iodide (TBAI) in dichloromethane or with tin(IV) iodide and sodium iodide in 1,3-dimethylimidazolidin-2-one at room temperature produced the corresponding homoallylic alcohols. The carbonyl allylations probably proceeded via the reduction of tin(IV) iodide to triiodostannate(II) species with iodide sources such as TBAl and Nal, which led to the construction of a tin(IV)-catalytic cycle based on regeneration of tin(IV) iodide via the transmetalation of homoallyloxytriiodotin to homoallyloxytrimethylsilane with iodotrimethylsilane. (c) 2005 Elsevier Ltd. All rights reserved.
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