Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Kobayashi, Ryo, once mentioned the application of 20059-73-8, Name is 2-(4-(Aminomethyl)phenoxy)-N,N-dimethylethanamine, molecular formula is C11H18N2O, molecular weight is 194.27, MDL number is MFCD01075231, category is ethers-buliding-blocks. Now introduce a scientific discovery about this category, Product Details of 20059-73-8.
Cleavage of C-O and C-H bonds in ethers by a genuine Si=O bond
An isolable three-coordinate dialkylsilanone without substantial electronic stabilization reacts with several ethers resulting in the cleavage of the C-O or C-H and C-O bonds in the ethers which have not been observed for the hitherto-known electronically stabilised isolable Si=O species. The formation of the Lewis base (DMAP and MTHP) complexes of the dialkylsilanone and the DFT calculations elucidated that the coordination of the ethereal oxygen atom to the Lewis acidic Si atom of the genuine Si=O bond is a key interaction for the reaction.
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